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Open Access Research Article

Impact of Pt-Ni Nanoparticle Architecture on Electrocatalytic Oxidation Reaction in Fuel Cells

Received: 04 September 2023;  Published: 16 November 2023;  doi: 10.21926/cr.2304027

Abstract

This paper investigates how the aggregation of bimetallic nanoparticles (NPs) influences the electronic condition of the surface adsorption site and, hence, the performance of materials during the electrooxidation of fuels in an alkaline medium. First, we synthesized Pt-Ni NPs in three configurations: ordered intermetallic, ordinary alloy, and core-shell. The NPs contained Pt and Ni close to a 1:1 Pt/Ni atomic ratio. They had similar particle sizes, which allowed us to evaluate their performance without the influen [...]

1426 7867

Open Access Review

Enzymes in Poly(Butylene-Succinate) Industry: An Overview on Synthesis Routes and Post-Processing Strategies

Received: 16 June 2023;  Published: 08 November 2023;  doi: 10.21926/cr.2304026

Abstract

This paper will present some sectors in which enzymes can replace traditional catalysts in poly(butylene-succinate) industry, emphasizing the green chemistry aspects associated with these newer strategies.

1515 12871

Open Access Original Research

Tungstophosphate Intercalated ZnAl Layered Double Hydroxide for Adsorptive and Visible Light Driven Photocatalytic Decolourisation of Organic Dyes

Received: 21 December 2022;  Published: 13 October 2023;  doi: 10.21926/cr.2304025

Abstract

Tungstophosphate (PW12O403-) intercalated ZnAl-Layered double hydroxide (ZnAl-PW12) was successfully synthesized through the rehydration of calcined LDH. Chemical analyses and characterizations by powder XRD, FT-IR, and Diffuse reflectance UV-Vis spectra confirmed the intercalation of PW12O403- ions equivalent to ~80% of the residual positive charge in the brucite layer. The efficiency of ZnAl-PW12 for decolourisation of four structurally different cationic/anionic dyes through simultaneous adsorption and photocata [...]

1250 8143

Open Access Short Review

Perovskite Oxide Thermoelectric Module - A Way Forward

Received: 27 July 2023;  Published: 11 October 2023;  doi: 10.21926/cr.2304024

Abstract

In the era of renewable and sustainable energy, perovskite materials remain pioneers as energy harvesting materials, be it thermoelectric waste heat harvesting or photovoltaic solar cell application. Oxide perovskite material is an emerging thermoelectric material in solving energy shortage issues through waste heat recovery. The chemical and structural stabilities, oxidation resistance, and cost-effective and straightforward manufacturing process are a few advantages of the oxide-based thermoelectric materials. Th [...]

1888 10428

Open Access Editorial

Nb2O5: Percentage Effect of T/H Phase and Evaluation of Catalytic Activity, a Preliminary Study

Received: 18 September 2023;  Published: 22 September 2023;  doi: 10.21926/cr.2303023

Abstract

Due to its similar characteristics to titanium, niobium has become an attractive alternative in photocatalytic processes. Research indicates that titania has an optimal percentage of phases resulting in a commercial catalyst, P25, that contains more than 70% anatase with a minor amount of rutile and a small amount of amorphous phase. On the other hand, for Nb2O5, percentage optimization was little explored in the literature, which consists of studying the phases obtained via heat treatment individually and in diffe [...]

1385 7690

Open Access Original Research

Enhancing Kerosene Selectivity of Fischer-Tropsch Synthesis by Periodical Pore Drainage Via Hydrogenolysis

Received: 27 June 2023;  Published: 12 September 2023;  doi: 10.21926/cr.2303022

Abstract

Accumulation of wax inside the catalyst pores during transient cobalt-catalyzed Fischer-Tropsch synthesis (FTS) leads to unfavorable product distribution and low activity by imposing internal mass transfer limitations. The condensation of paraffin severely changes the apparent product stream that actually leaves the reactor before the catalyst pores are filled completely and the steady state is reached. Thus, the product distribution of the transient FTS is less complex than expected in comparison to the steady-sta [...]

1690 13009

Open Access Original Research

Research and Application of Modified ZSM-5 for the Process of Alkylation of Oil Distillate Fractions

Received: 20 April 2023;  Published: 10 August 2023;  doi: 10.21926/cr.2303021

Abstract

In the oil distillate fraction alkylation process, a modified Zr zeolite ZSM-5 was obtained and studied. The modification was executed using a method that impregnated ZSM-5 with a 5% solution of ZrOCl2∙6H2O. X-ray diffraction studies were conducted on zeolite ZSM-5, zirconyl chloride modifier ZrOCl2∙6H2O, and modified zeolite ZSM-5-ZrO2, which was calcined at temperatures of 200, 400, and 550°C. The results revealed that the phase composition of modified ZSM-5-ZrO2 zeolite samples varied depending on the calcinatio [...]

1023 7383

Open Access Review

Recent Development of Photocatalytic Application Towards Wastewater Treatment

Received: 15 April 2023;  Published: 05 July 2023;  doi: 10.21926/cr.2303020

Abstract

With increasing population levels and rapidly growing industries worldwide, the purification of water contaminated with different impurities is one of the biggest challenges we face in recent times. Photocatalysis holds great potential as an efficient mineralization process to remove the foreign matter present in wastewater. Rapid advancement in innovative materials development has made photocatalysis the frontrunner among different water treatment methods. Our main priority lies in different strategic approaches t [...]

2123 16585

Open Access Research Article

Production and Characterization of Carboxymethylcellulase by Submerged Fermentation of Moniliophthora perniciosa

Received: 24 December 2022;  Published: 12 June 2023;  doi: 10.21926/cr.2302019

Abstract

Microorganisms that are capable of degrading lignocellulolytic materials can produce extracellular cellulase complexes. Microorganisms are an excellent alternative for the production of cellulolytic complex, since these sources have a high power of multiplication. In this work, we researched the production by the fungus Moniliophthora perniciosa. The production and pH and temperature optimum optimization were studied by Response surface methodology and carboxymethylcellulase (CMCase) characterization. Thermal stabi [...]

1056 7258

Open Access Research Article

Influence of Bifunctional PtZn/SiO2 and H-ZSM-5 Catalyst on the Rates and Selectivity of Propene Aromatization

Received: 28 March 2023;  Published: 06 June 2023;  doi: 10.21926/cr.2302018

Abstract

Previous studies on the conversion of olefins to aromatics with bifunctional Ga- or Zn-ZSM-5 catalysts have concluded that benzene, toluene, and xylenes (BTX) yields are significantly higher than for ZSM-5 alone. These results were attributed to the higher aromatic dehydrogenation rate of Ga or Zn. In this study, a highly active, bifunctional PtZn/SiO2 (1.3 wt% Pt, 2.6 wt% Zn) with H-ZSM-5 (Si/Al = 40) catalyst is investigated for propene aromatization at 723 K and 823 K. At low to moderate propene conversions, in [...]

1165 9192

Open Access Original Research

Synthesis and Characterization of MCM-41 Nanomaterials Containing Titanium and Application for Catalytic Oxidation of BTEX

Received: 17 August 2022;  Published: 30 May 2023;  doi: 10.21926/cr.2302017

Abstract

The TiO2/MCM-41 nanomaterials were synthesized by impregnation with an excess solvent with different percentages of titanium dioxide. They were used for catalytic degradation of Benzene Toluene Ethylbenzene and Xylenes (BTEX) in the presence of hydrogen peroxide in aqueous media. The obtained materials were characterized by X-ray Diffraction, nitrogen adsorption-desorption using the BET method and Fourier Transform Infrared Spectroscopy. The nanostructured phase of the hexagonal ordered materials was obtained even [...]

1572 9842

Open Access Research Article

Obtaining TiO2 Nanostructures by Electrospinning and Analysis of Absorbance in the UVA Spectrum for Photocatalytic Application

Received: 14 December 2022;  Published: 17 April 2023;  doi: 10.21926/cr.2302016

Abstract

The synthesis of fibers by electrospinning allows for obtaining nanostructures of one-dimensional materials with good flexibility, optical and catalytic properties, high surface area and porosity. They can be used in applications such as: catalysts, solar cells, fuel cells, membranes, and hydrogen batteries, among others. Here we emphasize that few reports in the literature describe the existing synergism between the optical and photocatalytic properties of TiO2, and the influence of this synergism on the formation [...]

959 7397

Open Access Original Research

Organic Structure-Directing Agent Free Synthesis of Mordenite with Seeds, Used as A Support for Mo Catalysts in the Transesterification of Soybean Oil

Received: 20 December 2022;  Published: 07 April 2023;  doi: 10.21926/cr.2302015

Abstract

This work prepared mordenite using seeds and without organic structure-directing agents (OSDAs). The Mo/Mordenite was prepared through wet impregnation and the catalysts’ performance was checked for transesterification of soybean oil with methanol. The mordenite zeolite was prepared through hydrothermal crystallization under static conditions with a molar composition of 6Na2O:Al2O3:30SiO2:780H2O. The catalyst samples were characterized crystallinity through X-ray diffraction, elemental composition by X-ray fluoresc [...]

1144 8875

Open Access Original Research

Spectrophotometric and Spectrofluorimetric Quantification of Urea via Silver Nanoparticles Prepared by Wet Chemical Method

Received: 09 November 2022;  Published: 15 March 2023;  doi: 10.21926/cr.2301014

Abstract

Silver nanoparticles have been utilized in an easy, sensitive, and effective approach through spectrophotometry and spectrofluorimetry to quantify urea in water samples. Here, 1,3-di-(1H-imidazole-1-yl) -2-propanol (DIPO) was employed to stabilize Ag NPs produced from the reduction of aqueous silver nitrate by sodium borohydride (NaBH4). Beer-Lambert's law was applied for determination using the complexation of Ag NPs with urea molecules. The results show urea can be assessed concurrently with good results and perc [...]

1748 13559

Open Access Original Research

Cost-Effective Biodiesel Synthesis from Waste Marble Powder as A Green Heterogeneous Catalyst Using Pongamia Pinnata Oil

Received: 08 December 2022;  Published: 13 March 2023;  doi: 10.21926/cr.2301013

Abstract

Waste marble powder (WMP) is Investigated for developing heterogeneous catalysts by calcination method and used in biodiesel synthesis by esterification-transesterification process from Pongamia Pinnata oil. Hammet indicators, Fourier transform infrared (FT-IR), Thermogravimetric analysis, and X-ray powder diffraction (XRD) techniques were also studied for the characterization of developed catalyst from waste marble powder (WMP). The conversion of calcium carbonate to calcium oxide in marble powder was found at 800 [...]

1465 9690

Open Access Original Research

Sustainable Synthesis of Zeolitic Imidazolate Framework-8 Nanoparticles and Application in the Adsorption of the Drug Chlorhexidine

Received: 06 December 2022;  Published: 13 March 2023;  doi: 10.21926/cr.2301012

Abstract

In an attempt to synthesize nanomaterial concerning chemistry, the sustainable synthesis of Zeolitic Imidazolate Framework-8 (ZIF-8) nanoparticles by a low-cost approach through the recycling of waste mother liquors was explored and then indicated the potential to remove chlorhexidine (CHLX) from an aqueous solution. ZIF-8 was produced under solvothermal reaction at 25°C and characterized by Fourier Transform Infrared Spectroscopy, X-ray diffraction, adsorption/desorption of N2, dynamic light scattering and con [...]

2021 15232

Open Access Research Article

Morpholine-Based Novel Ionic Liquid for Synthesis and Characterization of Triazolidinethiones and Their Biological Properties

Received: 03 December 2022;  Published: 12 March 2023;  doi: 10.21926/cr.2301011

Abstract

Keeping the green chemistry approach in mind we have synthesized a novel morpholine-based ionic liquid [NBMMorph]+Br-. The structure of Ionic liquid was confirmed by spectral techniques viz. IR, 1H NMR, and 13C NMR, analysis. The synthesized novel IL [NBMMorph]+Br- was utilized to prepare 1,2,4-triazolidine-3-thiones of biological significance. The [NBMMorph]+Br- IL shows excellent catalytic activity, and a simple filtration technique can separate the thiazolidinedione products. The structure of the synthesized com [...]

1719 10775

Open Access Original Research

Adsorption of Rhodamine-B (RhB) and Regeneration of MCM-41 Mesoporous Silica

Received: 01 November 2022;  Published: 01 March 2023;  doi: 10.21926/cr.2301010

Abstract

Rhodamine (RhB) adsorption was carried out on MCM-41 and MCM-41 calcined. The effect of parameters such as pH was investigated. The reusability potential of MCM-41 was also established and the mechanism of RhB adsorption was discussed. MCM-41 was synthesized and calcined, with all samples characterized by X-Ray Diffractometry, X-ray Fluorescence by Dispersive Energy, Infrared Spectroscopy, Scanning Electron Microscopy, and Thermogravimetric analysis. The results of the characterization techniques performed confirme [...]

1396 11005

Open Access Original Research

Methanol Synthesis Catalyst Waste as the Principal Component of New Sustainable Cementless Concrete

Received: 08 December 2022;  Published: 27 February 2023;  doi: 10.21926/cr.2301009

Abstract

Methanol synthesis catalyst (MSC) waste was applied as the principal component (till 70 wt.%) of sustainable ceramics in composites with bauxite processing waste (RM), and waste foundry sand (FS). The results of the initial components' chemical interaction studies by a complex of methods (XRD, SEM/EDS/mapping, AAS and LAMMA) during heating demonstrated the synthesis of amorphous glasslike new formation, their filling of pores and compaction of the ceramic’s structure. In this case, a strong chemical and mechanical [...]

1129 8557

Open Access Research Article

Enzymatic Hydrolysis of Meat Waste for a Circular Economy

Received: 30 December 2022;  Published: 16 February 2023;  doi: 10.21926/cr.2301008

Abstract

This work demonstrates the possibility of implementing a technology that allows profitable value to be drawn from the meat waste from retail stores. Protein hydrolysate, collagen and fatty acids were recovered from meat waste through enzymatic hydrolysis using a mixture of enzymes: a protease (Alcalase) and a lipase (Resinase). Enzymatic hydrolysis was studied by response surface methodology (RMS). Four independent variables were used to study the response variables. The analysis showed that all factors including p [...]

1581 10860

Open Access Original Research

Zn(OCOCH3)2·2H2O Catalysed Efficient Preparation of 2-Phenyl-4-Arylmethylidene-5-Oxazolinones under Ultrasonic Condition

Received: 30 September 2022;  Published: 15 February 2023;  doi: 10.21926/cr.2301007

Abstract

2-Phenyl-4-arylmethylidene-5-oxazolinones were synthesized in very high yield by subjecting a mixture of an aryl aldehyde/heterocyclic aldehyde/cinnamaldehyde and hippuric acid in anhydrous acetic anhydride and catalytic Zn(OCOCH3)2·2H2O to ultrasonication at 35 KHz for 4 to 8 min. This method has many advantages: use of a green catalyst; yields are high, involves easy workup procedure, is energy efficient and economically feasible.

1373 7940

Open Access Research Article

The Effects of Ge Substrate Surface States and Au Catalyst Layer Thickness on the Growth of Different GexOy Nanomaterials and Nanocrystals Configurations Using Vapor-Liquid-Solid Method with two Steps Temperature Mode

Received: 01 September 2022;  Published: 31 January 2023;  doi: 10.21926/cr.2301006

Abstract

Recently the GexOy nanomaterials have been studying intensively due to their interesting electronic materials, which have many particular properties and applications in nanotechnology and nano-devices fabrication. Much work has been done on many different synthesis methods and their properties of Ge and GexOy nanomaterials. However, the effects of the different Ge substrate surface states and Au catalyst layer thicknesses on the formation of different forms/morphologies of nanomaterials (nanowires, nanorods, nanopa [...]

1038 9022

Open Access Original Research

Pd-Ni-B/C Nanocatalysts for Electrochemical Oxidation of Ethanol in Alkaline Media

Received: 06 September 2022;  Published: 19 January 2023;  doi: 10.21926/cr.2301005

Abstract

This paper describes the synthesis of Pd0.70-Nix-By nanoparticles (x:y = 0.30:0, 0:0.30, 0.25:0.05, 0.20:0.10, 0.15:0.15, and 0.10:0.20) supported on carbon Vulcan XC-72 R by the chemical reduction method using ethylene glycol as a reducing agent for the study of the electrochemical oxidation of ethanol in alkaline media. Neither surfactants nor templates were used during the syntheses. The catalysts were physically characterized by transmission electron microscopy that showed the formation of nanoparticles with di [...]

1605 10255

Open Access Original Research

Fungal Laccase-Mediated Enhancement of the Bioactivity of Green Algae Extracts

Received: 01 December 2022;  Published: 19 January 2023;  doi: 10.21926/cr.2301004

Abstract

Biomass derived from green marine macroalgae Ulva sp. is considered a rich source of bioactive compounds. In the present study, we demonstrate the increased bioactivity of a phenolic-rich extract derived from green marine macroalgae Ulva intestinalis after its treatment with fungal laccases from Trametes versicolor and Agaricus bisporus. The phenolic composition of the extract, before and after its enzymatic treatment, was determined through several analytical methods. Furthermore, the antioxidant, enzyme-inhibitor [...]

1857 11349

Open Access Editorial

Acknowledgement to Reviewers of Catalysis Research in 2022

Received: 04 January 2023;  Published: 04 January 2023;  doi: 10.21926/cr.2301003

Abstract

The editors of Catalysis Research would like to express their sincere gratitude to the following reviewers for assessing manuscripts in 2022. We greatly appreciate the contribution of expert reviewers, which is crucial to the journal’s editorial process. We aim to recognize reviewer contributions through several mechanisms, of which the annual publication of reviewer names is one. Reviewers receive a voucher entitling them to a discount on their next LIDSEN publication and can download a certificate of recogn [...]

736 5140

Open Access Research Article

Iron Doped Titania/Polyaniline Composite: An Efficient Electrocatalyst for Hydrogen Evolution Reaction in Acidic Medium

Received: 15 September 2022;  Published: 04 January 2023;  doi: 10.21926/cr.2301002

Abstract

The development of noble metal-free catalyst for hydrogen evolution reaction (HER) is the primary challenge in fuel production to replace fossil fuels. Here, we have synthesized Fe-doped TiO2/PANI nanocomposite via facile in situ polymerization method and studied its electrocatalytic activity towards HER. The composite catalyzes HER efficiently with an overpotential value of -180 mV vs. RHE in 0.5 M H2SO4 solution to achieve the current density of 10 mA cm-2 and also possesses unique stability of 8 h. However, a un [...]

1356 8690

Open Access Research Article

Enhancement of Fischer-Tropsch Synthesis by Periodical Draining of the Wax-Filled Pores of a Cobalt Catalyst by Hydrogenolysis

Received: 27 September 2022;  Published: 03 January 2023;  doi: 10.21926/cr.2301001

Abstract

Fischer-Tropsch reactors operated in a steady state suffer from a low pore effectiveness factor and a high methane selectivity caused by internal mass transfer limitations due to the accumulation of long-chain hydrocarbons inside the catalyst pores. Therefore, an alternating process switching between Fischer-Tropsch synthesis (FTS) and drainage of the pores by hydrogenolysis is proposed. The periodical cracking of the accumulated waxes within the (partially) filled pores, realized by a switch from syngas (H2, CO) t [...]

1712 14082

Open Access Research Article

Ethanol Oxidation on Gold Nanowire Containing Oxygen Impurities: A Study by Ab Initio Molecular Dynamics Simulations

Received: 10 October 2022;  Published: 14 December 2022;  doi: 10.21926/cr.2204043

Abstract

Linear atomic chain (LAC) gold nanowires (Au-NWs) containing oxygen impurities are materials that could be used as supports to stimulate chemical reactions. Its peculiar structural characteristics, such as abnormal Au-Au bonds, make it interesting to explore the chemical reactions of this material at a theoretical level. This work investigated the chemical reaction of ethanol supported on Au-NW containing two oxygen impurities. Using ab initio molecular dynamics simulations, it was shown that the presence of oxygen [...]

1611 8333

Open Access Original Research

Fabrication and Catalytic Property of an Ordered Terpyridine Pd(II)/Ni(II) Catalytic Monolayer for Suzuki Coupling Reactions

Received: 21 September 2022;  Published: 02 December 2022;  doi: 10.21926/cr.2204042

Abstract

Fabrication, arrangement, and controllable composition of ordered organometallic films are critical for designing a highly active catalyst and investigating the catalytic mechanism. In this paper, an organometallic terpyridine Pd(II)/Ni(II) monolayer linked on the silicon substrate surface (denoted as Si-Tpy-Pd1/Ni1) was prepared and characterized using water contact angle, ultraviolet spectra, X-ray diffraction, scanning electron microscopy, and X-ray photoelectron microscopy. Si-Tpy-Pd1/Ni1 exhibited high catalyt [...]

1003 7431

Open Access Communication

Biocatalyzed Hydrolysis of Residual Oils and Proteins from Flax and Camelina Oilseed Press Cakes Using Lipase and Protease

Received: 14 September 2022;  Published: 17 November 2022;  doi: 10.21926/cr.2204041

Abstract

In this study, a PoC (Proof of Concept) of a possible biomass valorization of flax and camelina oilseed press cakes was presented. Biocatalyzed hydrolysis of residual oils and proteins extracted from these wastes was studied. The biotransformation of oils was performed using commercial immobilized lipases, including Amano PS, Amano AK, and Candida Antarctica Lipase B (CALB). Acylglycerols were partially or fully hydrolyzed using Amano PS and AK. Triglycerides were not hydrolyzed by CALB, which behaved differently. [...]

1318 7350

Open Access Research Article

Effect of Different Additives on the Structure and Activity of β-Galactosidase Immobilized on a Concanavalin A–Modified Silica-Coated Titanium Dioxide Nanocomposite

Received: 06 August 2022;  Published: 17 November 2022;  doi: 10.21926/cr.2204040

Abstract

Interpreting the relationship between the activity and structure of β-galactosidase is necessary to perceive the impact of the enzyme’s conformation on its catalysis. The current study thoroughly explains the effects of additives such as ethylenediaminetetraacetic acid (EDTA), sodium dodecyl sulfate (SDS), dithiothreitol (DTT), and urea on β-galactosidase activity and structure. β-Galactosidase activity was determined at various ionic strengths and temperatures as a function of time. Structural [...]

1367 9134

Open Access Original Research

Enhanced Photocatalytic Degradation of p-Nitrophenol and Phenol Red Through Synergistic Effects of a CeO2-TiO2 Nanocomposite

Received: 24 July 2022;  Published: 03 November 2022;  doi: 10.21926/cr.2204039

Abstract

Organic compounds are one of the most severe pollutants occurring in the environment. Hence, it is important to remove these compounds from the environment through remediation processes such as photocatalysis. The present study investigated the photocatalytic degradation of p-nitrophenol (NP) and phenol red (PR) using a cerium oxide-titanium oxide nanocomposite (CeO2-TiO2nc) under UV light. CeO2-TiO2nc was synthesized using the co-precipitation method. An X-ray diffraction (XRD) analysis confirmed the phase purity [...]

2126 10634

Open Access Original Research

Thermokinetic and Thermodynamic Parameters for Catalytic Pyrolysis of Medium Density Fiber over Ni/Beta Zeolite

Received: 31 August 2022;  Published: 02 November 2022;  doi: 10.21926/cr.2204038

Abstract

Catalytic pyrolysis is an attractive alternative for converting biomass into energy and chemicals to replace fossil sources. This has encouraged the search for efficient catalysts that can directly remove oxygenated products during pyrolysis, since they are the main problem in the processing and use of the products obtained. The catalytic and non-catalytic pyrolysis of medium density fiber (MDF) over beta zeolite-supported nickel (3 and 5%) was performed using the biomass/catalyst of 1.0/0.2 ratio. The thermokineti [...]

1790 10173

Open Access Original Research

The Effect of Oxygen-containing Additives in Feedstock on the Performance of the Catalytic Cracking Process

Received: 28 July 2022;  Published: 26 October 2022;  doi: 10.21926/cr.2204037

Abstract

In this study, we found that adding catalytic cracking feedstock, vacuum gas oil, and naphthenic acids in the amount of 0.005–0.0075% vol. increased the liquid target fractions, i.e., gasoline and light gas oil. The decrease in the yield of hydrocarbon gas at a practically constant degree of conversion of the raw material indicated a small proportion of the reactions of re-cracking of the resulting products. This also indicated the resource-saving nature of the process, allowing a larger amount of gasoline fraction [...]

1173 7192

Open Access Research Article

Short Hydroacylation-Based Synthesis of Four Aryl-3-hydroxypropanones, Predictable Biomass-Derived C9 Platform Molecules

Received: 22 July 2022;  Published: 26 October 2022;  doi: 10.21926/cr.2204036

Abstract

A two-step protocol for the synthesis of aryl-3-hydroxypropanones, which were regarded as lignin degradation products, was proposed herein. This protocol provided a more rapid and easier access to aryl-3-hydroxypropanones, and aryl-3-hydroxypropanones were expected to be ideal platform molecules for the synthesis of more complex value-added targets.

1519 8015

Open Access Original Research

Effect of ZSM-5 Particle Size and Framework Silica-to-Alumina Ratio on Hexane Aromatization

Received: 13 August 2022;  Published: 17 October 2022;  doi: 10.21926/cr.2204035

Abstract

Parent ZSM-5 and Ga-modified ZSM-5 catalysts with different Si/Al ratios and particle sizes were prepared. The physicochemical properties of the prepared catalysts were investigated by performing X-ray powder diffraction analysis, BET surface area analysis, and NH3-TPD analysis. The performance of the aromatization reaction of the prepared catalysts was evaluated with 1-hexane as a model compound. The zeolite catalysts with a low SiO2/Al2O3 ratio possessed better activity than those with a high SiO2/Al2O3 ratio. Ga [...]

2039 14187

Open Access Research Article

Kinetic Modeling of the Esterification of Oleic Acid and Methanol in Conventional and Adsorptive Reaction Systems

Received: 23 August 2022;  Published: 17 October 2022;  doi: 10.21926/cr.2204034

Abstract

Biodiesel is derived from renewable vegetable or animal sources and is either used as a standalone fuel or blended with oil-based diesel. The kinetic mechanism of the esterification of oleic acid was investigated in a conventional batch reactor and a batch reactor coupled to a water adsorption system. The esterification was performed with oleic acid and methanol at different temperatures (70 to 110 °C) and alcohol-to-oleic acid molar ratios (3:1 to 9:1), using sulfuric acid as a catalyst. A kinetic model was constr [...]

3894 19813

Open Access Review

Perovskite Solar Cells: Assessment of the Materials, Efficiency, and Stability

Received: 14 August 2022;  Published: 14 October 2022;  doi: 10.21926/cr.2204033

Abstract

Solar cells based on organic-inorganic lead halide perovskites are popular in the photovoltaic community due to their high efficiency, low cost, and solution processability. Understanding the fundamentals of metal halide perovskite and its interfaces is extremely important for achieving high-quality materials and developing efficient devices using these materials with the necessary properties. Various methodologies have been used to evaluate the excellent optoelectronic properties, efficiency, and stability of PSCs [...]

4368 33540

Open Access Original Research

3D Printed Polylactic Acid (PLA) Well Plates for Enzyme Inhibition Studies: The Case of Pancreatic Lipase

Received: 31 July 2022;  Published: 08 October 2022;  doi: 10.21926/cr.2204032

Abstract

3D printed PLA has already been demonstrated for several biotechnological applications, including enzymes immobilization. The prerequisites for an efficient screening assay include using small volumes of reagents, low cost, and rapid screening of large numbers of compounds and extracts. Hence, assays based on microtiter plates are predominant. Thus, designing and fabricating scaffolds on a similar scale, which could serve as immobilization carriers, and their recruitment in inhibitors screening studies is of great [...]

1368 8725

Open Access Original Research

Catalytic Co-gasification of Lignites Blended with a Forest Residue under the Carbon Dioxide Stream

Received: 24 May 2022;  Published: 29 September 2022;  doi: 10.21926/cr.2203031

Abstract

The present study investigated the co-gasification of two different lignites blended with the forest residue collected from the land restoration activity sites of open-pit mines located in the region of the Ptolemais basin in North Greece performed under the carbon dioxide stream. All samples were devolatilized in a fixed bed unit prior to the gasification evaluations. The gasification evaluations were performed using a thermal analysis system (TG/DTG) operated at temperatures of up to 1000 °C. The reactivity, [...]

1071 6100

Open Access Original Research

Effect of Microwave Radiation on the Development of a Porous Aluminum Carrier of the Active Mass of Catalysts in Heterogeneous Catalytic Reactions

Received: 24 June 2022;  Published: 26 September 2022;  doi: 10.21926/cr.2203030

Abstract

In this study, we prepared a fine-grained, aluminum-reinforced alumina support matrix of the active mass of catalysts, which showed activity in heterogeneous catalytic reactions stimulated by electromagnetic radiation in the microwave range. The support absorbed microwave radiation of 2.45 GHz. We compared the textural characteristics of samples of Al/Al2O3 supports obtained by conventional heat treatment to those synthesized by heat treatment in a microwave field. We found several advantages of heat treating poten [...]

1483 7055

Open Access Review

Microbial Cyclodextrin Glycosyltransferases: Sources, Production, and Application in Cyclodextrin Synthesis

Received: 11 June 2022;  Published: 22 September 2022;  doi: 10.21926/cr.2203029

Abstract

Cyclodextrin glycosyltransferase (CGTase) is a multifunctional enzyme that hydrolyzes the α-glycosidic bond between two sugar molecules and synthesizes cyclodextrins (CDs) and other transglycosylation products. It is a ubiquitously present extracellular enzyme that offers the CGTase-producing organism the sole right onto starch substrates over other microbes. The present review provides a brief account of diversity among CGTase-producing microbes, CGTase production in different heterologous hosts (wherein ext [...]

3290 23747

Open Access Original Research

Heterologous Expression, Characterization, and Comparison of Laccases from the White Rot Causing Basidiomycete Cerrena Unicolor

Received: 26 July 2022;  Published: 20 September 2022;  doi: 10.21926/cr.2203028

Abstract

Lignin is the most abundant renewable source of aromatics on earth, and conversion of it to chemicals and fuels is needed to build an economically viable renewable biofuels industry. Biological routes to converting lignin to fuels and chemicals involve depolymerizing lignin using lignin-degrading enzymes that catalyze the breaking of ether and carbon-carbon bonds in the phenolic and non-phenolic subunits of lignin. Laccases are a crucial class of lignin-degrading enzymes and are copper-containing enzymes capable of [...]

1428 8673

Open Access Research Article

Effective Cu/ZnO/Al2O3 Catalyst for Methanol Production: Synthesis, Activation, Catalytic Performance, and Regeneration

Received: 09 September 2021;  Published: 19 September 2022;  doi: 10.21926/cr.2203027

Abstract

A precursor CuO/ZnO/Al2O3 catalyst for methanol synthesis has been prepared at room temperature by introducing a ternary salt solution into the excess of sodium carbonate solution following the reverse co-precipitation method. The catalyst was tested for the synthesis of methanol from synthesis gas. The composition (vol. %) has been presented: CO, 22; CO2, 5.8; N2, 5.5; H2, balance. The methanol productivity was recorded to be 2.7 kg kgcat–1 h–1 at a temperature of 260 °С, a pressure of 3 MPa, and a [...]

4065 36230

Open Access Review

Design of Heterogeneous Catalysts for the Conversion of Furfural to C5 Derivatives: A Brief Review

Received: 30 June 2022;  Published: 13 September 2022;  doi: 10.21926/cr.2203026

Abstract

Technological development made in the field of biomass application allows synthesizing several high-value products, such as furfuraldehyde. Furfural, produced through sequential hydrolysis and dehydration reactions from biomass, is considered a platform molecule and a precursor of several other chemicals and biofuels that are generated following reactions such as hydrogenation, hydrodeoxygenation, and decarboxylation. This review aims to reveal the environmental-friendly mechanisms followed for producing furfural d [...]

2006 13741

Open Access Original Research

Removal of As(III) from Water by Cellulase Templated TiO2: A Photocatalytic Oxidation Conjugated Adsorption Process

Received: 16 July 2022;  Published: 09 September 2022;  doi: 10.21926/cr.2203025

Abstract

TiO2 photocatalyst was prepared using cellulase as a biotemplate through a hydrothermal process. The as-prepared catalyst was characterized based on physicochemical techniques and was used to remove As(III) from contaminated water. The cellulase templated TiO2 photocatalyst (TiO2-cellulase) had a large specific surface area, which reached 166.6 m2·g–1. It also had a strong oxidation ability and, thus, behaved well in both photocatalytic oxidation of As(III) and dark adsorption. The pH of the solution h [...]

1058 6811

Open Access Original Research

Biochemical Characteristics and Healing Activity of Bromelia laciniosa Leaf Protease

Received: 27 May 2022;  Published: 25 August 2022;  doi: 10.21926/cr.2203024

Abstract

Macambira plant (Bromelia laciniosa Mart. Ex Shult. & Schult. f.) is a species belonging to the family Bromeliaceae, which is distributed widely in the hinterlands of northeastern Brazil, from Bahia to Piauí states. The plants of this species contain an enzyme complex named bromelain, which has great potential for therapeutic applications. In the present study, bromelain derived from Bromelia laciniosa leaves was assessed for its thermodynamic properties and in vitro cytotoxic and healing activities. Bro [...]

1413 11549

Open Access Original Research

Fischer-Tropsch Synthesis on Co/SBA-15 Catalyst: Characterization and Oligomerization Modeling

Received: 05 May 2022;  Published: 16 August 2022;  doi: 10.21926/cr.2203023

Abstract

In this study, we investigated the oligomerization mechanism of the Fischer-Tropsch synthesis catalyzed by a cobalt-based catalyst supported by SBA-15. The Co/SBA-15 catalyst contained 20% w/w of cobalt. It was prepared by the wet impregnation method and characterized by X-ray diffraction (XRD), N2 adsorption-desorption, temperature-programmed reduction (TPR), and scanning electron microscopy coupled to X-ray energy dispersion spectroscopy (SEM-EDS). The FT synthesis was conducted in a slurry bed reactor operating [...]

1566 8589

Open Access Original Research

Degradation of Amido Black Dye Using Ultra-Violet Light Catalyzed by Iron Oxide Nanoparticles: Kinetics and Mechanism of Degradation

Received: 26 June 2022;  Published: 25 July 2022;  doi: 10.21926/cr.2203022

Abstract

In this study, we investigated the degradation of amido black dye in an aqueous solution using ultra-violet (UV) light catalyzed by iron oxide nanoparticles (nano-Fe). The nano-Fe was synthesized by sodium borohydride reduction of ferric chloride solution and was characterized by scanning electron microscopy (SEM), X-ray diffraction (XRD), and X-ray fluorescence spectrophotometry (XRF). The SEM of the nano-Fe showed regular spherical particles, the XRD examination showed a weak and broad peak at Fe (1 1 0), and the [...]

1396 8621

Open Access Original Research

Hydrocracking of Di-and Triaromatic Hydrocarbons to Monoaromatics over Mixed Bi-functional Catalysts

Received: 10 January 2022;  Published: 19 July 2022;  doi: 10.21926/cr.2203021

Abstract

In this study, we present selective hydrocracking of poly (di and tri) aromatic compounds to monoaromatics, such as benzene, toluene, and xylenes (BTX), over a mixture of Pt/Al2O3 and Y zeolites. The polyaromatic compounds feed is a combined simulated model feed, which is similar to light cycle oil (LCO) in composition. The feed is processed in a fixed bed reactor over a catalyst mixture: in the first step, selective hydrogenation of di and tri-aromatic compounds occurs in the presence of Pt/Al2O3 catalyst, followe [...]

1994 11563

Open Access Original Research

Homogeneous {Ti2Ni} Heterotrinuclear Catalyst for Ethylene Polymerization and Copolymerization

Received: 18 May 2022;  Published: 06 July 2022;  doi: 10.21926/cr.2203020

Abstract

We synthesized and spectroscopically characterized a new heterotrimetallic {Ti2Ni} ethylene (co)polymerization precatalyst containing one (α-diimine)NiBr2 and two (phenoxy-imine)TiCl4 scaffolds. Its calculated structure was investigated at the DFT B3LYP/LACVP** level. Our calculations showed that the titanium(IV) centers were in a slightly distorted trigonal bipyramidal environment, and the average Ti···Ni distance was 8.76 Å. The precatalyst was used for synthesizing polyethylene a [...]

1374 10561

Open Access Review

Zeolite-Containing Catalysts in Alkylation Processes

Received: 05 May 2022;  Published: 05 July 2022;  doi: 10.21926/cr.2203019

Abstract

This article provides an overview of zeolite-containing catalysts used in the alkylation of benzene and toluene with olefins, isobutane with butenes and butane-butene fractions, gasoline and oil fractions with olefins, propane-propylene, and butane-butylene fractions of catalytic cracking. Zeolites have various types of structures, including BEA, MFI, MWW, FAU, etc., which differ in pore size and the number and location of the channels. High-silica zeolites have a large pore volume, high acidity, good hydrothermal [...]

4358 22723

Open Access Research Article

Co2+ Doping and Molecular Adsorption Behavior of Anatase TiO2 (001) Crystal Plane

Received: 10 May 2022;  Published: 04 July 2022;  doi: 10.21926/cr.2203018

Abstract

TiO2 (001) crystal plane exhibits molecular adsorption and photocatalytic activity. The loading capacity of reactive oxygen species present on crystal planes helps in the significant improvement of catalytic activity. The methods of synthesis and conditions of existence significantly affect the molecular adsorption properties of crystal planes, which in turn affects the ability of the system to load reactive oxygen species. Herein, we report the simulation of the molecular adsorption behavior on the TiO2 (001) usin [...]

1297 9055

Open Access Original Research

Dearomatization of the Kerosene Fraction: Kinetic Studies

Received: 09 January 2022;  Published: 28 June 2022;  doi: 10.21926/cr.2202017

Abstract

The kinetics of dearomatization of a kerosene fraction processed using a zeolite catalyst (0.9 HZSM-5) at different temperatures (160-200°C), the molar ratio between the aromatic hydrocarbons present in the kerosene fraction and n-decene (1:(0.5-4)), and the reaction time (1-3 h) were studied. Based on the obtained data, a kinetic model for kerosene dearomatization is proposed. It is assumed that the single-center Riedel mechanism is followed. The stage associated with the interaction between n-decene adsorbed on t [...]

1472 8728

Open Access Research Article

3D Fe3O4-decorated Nitrogen-doped Graphene Aerogel as a Highly Durable Electrocatalyst for Oxygen Reduction Reactions

Received: 29 April 2022;  Published: 21 June 2022;  doi: 10.21926/cr.2202016

Abstract

The rational design of efficient electrocatalysts for oxygen reduction reaction (ORR) is the key to developing fuel cells and metal-air batteries. Carbon-supported iron-based materials, as the most promising electrocatalysts for ORR, have drawn much attention as they are cost-effective and exhibit high activity. In this work, a three-dimensional (3D) Fe3O4-decorated N-doped graphene aerogel (Fe3O4/NGA) catalyst was synthesized following a simple hydrothermal method which was followed by an annealing process. The co [...]

1664 10171

Open Access Original Research

Synthesis of a Solid Base Catalyst Formed from Zinc(II) Acetylacetonate and Consisting of MgO Modified with ZnO

Received: 28 April 2022;  Published: 06 June 2022;  doi: 10.21926/cr.2202015

Abstract

Solid base catalysts consisting of MgO modified with 10 mol% ZnO (ZnO/MgO) were prepared by depositing zinc(II) acetylacetonate (Zn(acac)2) in polar and nonpolar organic solvents on the surface of MgO and Mg(OH)2. The process was followed by thermal decomposition in air at 773 K over a period of 3 h. The activity of MgO modified with Zn(acac)2 for base-catalyzed retroaldol reaction (the decomposition of diacetone alcohol (4-hydroxy-4-methyl-2-pentanone) to acetone) at 299 K was higher than the activity of unmodifie [...]

1190 9243

Open Access Original Research

Visible-Light-Induced Formation of Aromatic Ketones: A Metal-Free C−H Oxygenation Process in Air under Room Temperature

Received: 01 April 2022;  Published: 10 May 2022;  doi: 10.21926/cr.2202014

Abstract

The process of light-induced C-H oxygenation is of high interest as it can be used for the construction of oxygenated compounds. Herein, we report a mild and general method for the efficient synthesis of aromatic ketones following the process of metal-free C-H oxygenation. With air as the oxidant, high functional tolerance was demonstrated, and the desired ketones were obtained in moderate to excellent yields at room temperature (25 oC). Mechanistic studies suggested that the oxidative transformation potentially oc [...]

1393 10067

Open Access Review

Lipases: Sources of Acquisition, Ways of Production, and Recent Applications

Received: 16 February 2022;  Published: 07 May 2022;  doi: 10.21926/cr.2202013

Abstract

Enzymes are extensively used in biotechnological processes in several areas of industry. They are sustainable and safe, and their specificity is another characteristic that improves the performance in the process. Among enzymes, lipase is relevant due to the ability to play different roles in the industry and the possibility of collecting them from microbial sources that are found in industrial residues. This can reduce the costs of enzyme production. In relation to that, lipase immobilization is an interesting pro [...]

2983 37782

Open Access Review

Recent Advances in the Application of Perovskite Catalysts in the Dry Reforming of Methane

Received: 29 January 2022;  Published: 26 April 2022;  doi: 10.21926/cr.2202012

Abstract

The use of the dry reforming of methane (DRM) to convert the two principal greenhouse gases, methane and carbon dioxide, to syngas (a mixture of H2 and CO) has attracted increasing attention in recent years. However, the DRM reaction suffers from the twin disadvantages of carbon deposition and sintering, so a highly efficient and robust catalyst with superior anti-deactivation properties is required. One way to meet this need is to incorporate active metals into crystalline oxides, such as perovskite. In this paper [...]

1735 13434

Open Access Original Research

Pd-Cu Bimetallic Based Catalysts for Nitrate Remediation in Water: Synthesis, Characterization, and the Influence of Supports

Received: 29 January 2022;  Published: 21 April 2022;  doi: 10.21926/cr.2202011

Abstract

The use of Pd-Cu bimetallic catalysts in the reduction of aqueous nitrate ions by hydrogen was studied. The catalysts were supported on multi-walled carbon nanotubes (MWCNTs), activated carbon (AC), and Titania, and the influence of the support on the nitrate reduction activity in water was then investigated. The catalysts were characterized before and after use by FT-IR, XRD, SEM, EDX, and Laser Granulometry. It was found that the surface characteristics of the support have an influence on the catalyst activity, w [...]

1604 11885

Open Access Communication

A New Chiral Cyclopalladated Ferrocenylimine Self-assembly Polymeric Film supported on Silicon for Heck and Suzuki-coupling Reactions

Received: 21 March 2022;  Published: 14 April 2022;  doi: 10.21926/cr.2202010

Abstract

A new chiral cyclopalladated ferrocenyl imine catalyst (called 4a2) was designed and synthesized, and its self-assembly catalytic polymeric brush supported on silicon (denoted as Si@PB4a2) was also fabricated by surface-initiated atom transfer radical polymerization (ATRP) and characterized. The catalytic properties of monomer 4a2 in homogeneous and Si@PB4a2 in heterogeneous in Heck and Suzuki cross-coupling were investigated, respectively. They exhibited higher catalytic activity in Heck, and Suzuki coupling react [...]

1581 8803

Open Access Original Research

Hierarchical MFI Zeolite Catalysts: How to Determine Their Textural Properties?-A Comparative Study

Received: 26 January 2022;  Published: 14 April 2022;  doi: 10.21926/cr.2202009

Abstract

It is important to elucidate the role of the surface areas and pore volumes of hierarchical zeolites to understand their behavior as catalysts. Micro-and mesopore surface areas and volumes of the hierarchical MFI (Mobil Five zeolites) were assessed following several methods: (i) N2 adsorption at 77 K using classical and corrected t-plot analyses methods, (ii) pre-adsorption of n-nonane was followed by the study of the N2 adsorption at 77 K, and (iii) non-local-density functional theory (NLDFT) analysis using either [...]

2196 19609

Open Access Original Research

Preparation of a Novel Bi2MoO6/Ag/Ag2CrO4 Catalyst with Promoted Visible Light Photodegradation of RhB Dye

Received: 29 January 2022;  Published: 07 April 2022;  doi: 10.21926/cr.2202008

Abstract

A series of novel Bi2MoO6/Ag/Ag2CrO4 heterostructure photocatalysts (denoted as BA-X, X = 1, 3, 5, 10) were synthesized using a coprecipitation method. These photocatalysts were characterized by scanning electron microscopy (SEM), X-ray diffraction (XRD), UV-vis spectroscopy, and X-ray photoelectron spectroscopy (XPS) and their photocatalytic properties were investigated. Compared with pure Bi2MoO6 or Ag2CrO4, BA-5 exhibited a higher photocatalytic property and broader light absorption. In addition, the surface pla [...]

1531 11072

Open Access Research Article

The Use of Composite TiO2/Activated Carbon Fibers as a Photocatalyst in a Sequential Adsorption/Photocatalysis Process for the Elimination of Ciprofloxacin

Received: 20 January 2022;  Published: 15 March 2022;  doi: 10.21926/cr.2201007

Abstract

This work reports the performance of a sequential adsorption/photocatalysis process using activated carbon fibers with deposited TiO2 for the elimination of the antibiotic ciprofloxacin (CIP) in water. A commercial activated carbon fiber (ACF10) was selected as the support, and a TiO2 coating was synthesized using Metal Organic Chemical Vapor Deposition (MOCVD). Experiments were carried out using a photocatalytic reactor irradiated with monochromatic LEDs (365nm). Two different processes have been studied: adsorpti [...]

1488 10839

Open Access Review

Recent Progress in the Development of Molecular Electrocatalysts for Formate Oxidation

Received: 31 December 2021;  Published: 22 February 2022;  doi: 10.21926/cr.2201006

Abstract

Fuel cells based on renewable synthetic fuels are promising alternatives to fossil fuel combustion for efficient electricity production. Much focus has been placed on hydrogen as a chemical fuel, but being a flammable gas, there are challenges with its safe handling. Formic acid is an attractive liquid fuel for use in direct formic acid or formate fuel cells, and it can in principle be produced from the thermal or electrochemical reduction of carbon dioxide. Over the past ten years, advances have been made in the d [...]

1573 11662

Open Access Original Research

Determining the Band Alignment at the BiVO4|NiOOH Interface Using the Hybrid DFT Technique

Received: 29 November 2021;  Published: 21 February 2022;  doi: 10.21926/cr.2201005

Abstract

It is important to understand the band offsets between semiconductors, which are crucial to determine the direction of electron transfer at the interfaces. Two methods are normally used to determine the direction from the first principles: alternating slabs put in contact (without empty spaces between them) and separate calculations for each material surface in the presence of vacuum spaces. The first method may introduce distortions due to insufficient epitaxial match, which may lead to bandgap changes, and the se [...]

1383 9407

Open Access Communication

One-Pot Tandem Synthesis of Nitriles and Amides from Biomass Platform Compounds

Received: 28 December 2021;  Published: 21 February 2022;  doi: 10.21926/cr.2201004

Abstract

In recent years, research on converting biomass platform compounds into high-value chemicals and pharmaceutical intermediates has garnered huge interest. Nitrile and amide groups are key structures in natural products and biologically active molecules. The direct conversion of biomass platform compounds into nitriles and amides will undoubtedly be an important guide for biomass utilization. In this paper, a facile and efficient triphosgene-assisted one-pot conversion for aldehydes and ketones into nitrile and amide [...]

3005 15405

Open Access Original Research

Controllable Cyclopalladated Polythiophene Imine Monolayer by Self-Assembly, Hybrid Doping and Electrochemical Polymerization: A Simple Way to Enhance Activity and Stability

Received: 13 December 2021;  Published: 03 February 2022;  doi: 10.21926/cr.2201003

Abstract

In this article, an approach to generate self-assembly cyclopalladated polythiophene imine monolayers (denoted as ITO@Pd-CPTIMs) is described. The monolayers were fabricated by combining self-assembly (SA), hybrid doping (HD), and electrochemical polymerization (ECP) called SA-HD-ECP. The catalytic activity and stability of the polymerized monolayers in the Suzuki coupling reaction were improved by modulating the structure and morphology in hybrid doping using different thiophene derivatives, concentrations, and sc [...]

1800 10229

Open Access Original Research

Acetonitrile Combustion over Copper-Based Nanocatalysts: A Structure-Performance Relationship Study

Received: 01 December 2021;  Published: 26 January 2022;  doi: 10.21926/cr.2201002

Abstract

In this paper, the relationship between activity and structure of Cu2+ in different chemical environments of Cu-BETA, La2CuO4, and CuO nanocatalysts was systematically investigated for acetonitrile combustion. The study revealed that exchanged and octahedral species of Cu2+ coexist in Cu-BETA, while octahedral species are dominant in CuO and La2CuO4. All nanocatalysts achieved high conversion rates of acetonitrile, which rapidly increased with temperature. CuO and La2CuO4 led to the formation of undesired products [...]

1420 9366

Open Access Original Research

Versatility of Supported Gold Nanoparticles on Hydrotalcites used for Oxidation and Reduction Reactions

Received: 25 October 2021;  Published: 13 January 2022;  doi: 10.21926/cr.2201001

Abstract

Regardless of their size, supported gold nanoparticles are largely used for liquid-phase oxidation reactions. Small gold nanoparticles exhibit good performance during the reduction of organic compounds. The direct reduction of carboxylic acid to aldehyde is a famous and familiar reaction in the field of organic chemistry and is considered as one of the fundamental chemical transformations. Herein, we present Au/hydrotalcite, Au/MgO, and Au/Al2O3 systems as heterogeneous versatile catalysts to realize the oxidation [...]

1436 10453

Open Access Research Article

Effect of Acid Treatment on the Properties of Zeolite Catalyst for Straight-Run Gasoline Upgrading

Received: 10 October 2021;  Published: 01 December 2021;  doi: 10.21926/cr.2104004

Abstract

The objective of this research was to analyze the effect of different concentrations of nitric and hydrochloric acids on the structural, acidic, and catalytic properties of a post-synthetic treated ZSM-5 type zeolite at various temperatures. The properties of zeolite catalysts were determined using different methods, such as the Brunauer-Emmett-Teller (BET) method for specific surface area, temperature-programmed desorption (TPD) of ammonia method for acidic properties, and a flow-through unit with fixed bed cataly [...]

2995 16582

Open Access Original Research

Stability of a Fe-Rich Cathode Catalyst in an Anion Exchange Membrane Fuel Cell

Received: 09 June 2021;  Published: 16 September 2021;  doi: 10.21926/cr.2103003

Abstract

Fe-rich alloys have been widely studied as catalyst materials for the cathodic oxygen reduction reaction (ORR) in hydrogen fuel cells, and many have shown high activities. The stability of Fe-rich catalysts has also been researched, and some studies have shown promising results using an accelerated stress test (AST), which uses a potential cycling method. However, for commercial fuel cell applications, such as standby power systems, the catalyst has to tolerate a high potential for a long period, which can not be r [...]

1284 10422

Open Access Original Research

Photocatalytic Degradation of Azo Dyes Using Microreactors: Mechanistic Study of its Effects on H2O2 Addition

Received: 17 August 2021;  Published: 13 September 2021;  doi: 10.21926/cr.2103002

Abstract

The photocatalytic reaction involved in TiO2 photocatalysis was investigated using a microreactor coated with TiO2 film on the glass plate attached on one side of the microreactor. It was confirmed that the effect of H2O2 on the photocatalytic degradation efficiency of azo dyes (acid orange 7, acid red 151, and acid yellow 23) was dependent on the polymorphs (anatase and rutile) of TiO2 coated on the glass plate of the UV-irradiated microreactor. Scavengers of holes (KI) and electrons (p-benzoquinone) were added to [...]

1911 12247

Open Access Original Research

Development of an Efficient Bi-Functional Catalyst made of a Novel Hybrid Material for Rechargeable Zn-Air Battery

Received: 24 May 2021;  Published: 16 July 2021;  doi: 10.21926/cr.2103001

Abstract

One-pot synthesis of mesoporous hybrid material consisting of Mn-Co/CoO nanoparticles encapsulated in an N-doped graphene shell decorated with Mo2C nanoparticles (Mo2C-NC@Mn-Co/CoO) was reported. The Mn and Mo components synergistically refined the graphitized carbons due to the interactions with N and C atoms while promoting the stability of the Co/CoO nanoparticles. These components exhibited a beneficial effect on the dispersion of the active metal/metal oxide nanoparticles and the formation of a mesoporous stru [...]

4100 15988

Open Access Review

Contribution of Solar Energy to Buildings’ Energy Demands: A Review

Received: 27 June 2025;  Published: 12 January 2026;  doi: 10.21926/aeer.2601002

Abstract

Buildings account for a significant portion of global energy consumption, estimated at 30-40%, and also contribute to greenhouse gas emissions. Energy consumption in a building is mainly thermal (natural gas) and electrical. This energy is usually used for heating water, cooking, illumination, ventilation and air conditioning, powering appliances, floor heating, and other activities. These activities were examined, and their substitution by solar-based energy sources was reviewed. To achieve this objective, an exte [...]

151 402

Open Access Editorial

Acknowledgment to Reviewers of Advances in Environmental and Engineering Research in 2025

Received: 04 January 2026;  Published: 04 January 2026;  doi: 10.21926/aeer.2601001

Abstract

The editors of Advances in Environmental and Engineering Research would like to express their sincere gratitude to the following reviewers for assessing manuscripts in 2025. We greatly appreciate the contribution of expert reviewers, which is crucial to the journal's editorial process. We aim to recognize reviewer contributions through several mechanisms, of which the annual publication of reviewer names is one. Reviewers can download a certificate of recognition directly from our submission system. Additionally, r [...]

171 392

Open Access Editorial

Biochar and Circular Economy Approaches in Environmental Sustainability

Received: 21 December 2025;  Published: 24 December 2025;  doi: 10.21926/aeer.2504035

Abstract

The rising concerns of soil erosion, organic waste generation and global warming have shown the need to address them through multifaceted methods that transcend conventional linear models of resource utilization. Circular economy is a regenerative model that is anchored on caring about waste valorisation, resource effectiveness and environmental fortitude. In this paradigm, biochar has been developed as a multifunctional compound capable of integrating waste management, soil rehabilitation, climate control and rene [...]

241 864

Open Access Original Research

Environmental Risk Assessment of Antiretrovirals Consumed in Belo Horizonte, Brazil

Received: 09 June 2025;  Published: 04 December 2025;  doi: 10.21926/aeer.2504034

Abstract

The development and utilization of pharmaceuticals, notably antiretrovirals (ARVs), have significantly enhanced both human quality of life and life expectancy. Nevertheless, the excretion of these compounds into aquatic environments, often exacerbated by inadequate sanitation infrastructure, poses considerable risks to biota. This investigation evaluated the environmental impact of 14 ARVs consumed within the municipality of Belo Horizonte (BH), Brazil. The assessment employed the Environmental Risk Assessment (ERA [...]

307 1324

Open Access Original Research

GHG Emissions Management in Urban Areas by Interactive Road Traffic Control: Application of Artificial Intelligence

Received: 04 June 2025;  Published: 03 December 2025;  doi: 10.21926/aeer.2504033

Abstract

The rising pollution levels in congested urban areas pose a serious threat to human health. Many solutions have been proposed to control and reduce gas emissions from road traffic, with results that are not entirely satisfactory. The adoption of new techniques and methodologies for early detection of pollutant emissions may enable effective management and control of road traffic contamination. The proposed method introduces an interactive protocol that facilitates communication between the traffic control center an [...]

274 1165

Open Access Original Research

Cultural Cells: A Circular Economy-Driven Blueprint for Creative Tourism and Regional Revitalization in Greece

Received: 11 June 2025;  Published: 11 November 2025;  doi: 10.21926/aeer.2504032

Abstract

This study proposes a novel creative tourism model integrating artistic creation with circular economy principles to foster regional revitalization in North Euboea, Greece. Employing a case study approach, it develops the concept of “Cultural Cells”—dedicated hubs for artists and art students specializing in painting and sculpture—designed to enhance tourism through immersive engagement. The methodology combines qualitative analysis of regional cultural and environmental assets with theoretical estimates of circula [...]

477 2676

Open Access Original Research

Comparative Analysis of Healthcare Waste Legislation: Alignment and Discrepancies between Federal, State, and Municipal Regulations

Received: 02 July 2025;  Published: 11 November 2025;  doi: 10.21926/aeer.2504031

Abstract

The management of healthcare waste (HCW) presents a significant environmental and public health challenge, aggravated by gaps in current Brazilian federal regulations. This study provides a comprehensive analysis of specific state and municipal legislation on HCW, comparing it with ANVISA Resolution No. 222/2018 and CONAMA Resolution No. 358/2005 to ascertain whether local regulations enhance management practices and can act as supplementary instruments to federal guidelines. The methodology was structured into thr [...]

1134 5196

Open Access Interview

An Interview with Prof. Dr. Hanuman Singh Jatav

Received: 26 October 2025;  Published: 27 October 2025;  doi: 10.21926/aeer.2504030

289 1931

Open Access Editorial

Iron-Based Nanoparticles for Water and Soil Treatment

Received: 15 September 2025;  Published: 22 September 2025;  doi: 10.21926/aeer.2503029

723 3065

Open Access Review

Applications of Generative Large Language Models in Environmental Science: A Systematic Review

Received: 07 April 2025;  Published: 12 August 2025;  doi: 10.21926/aeer.2503028

Abstract

Environmental science addresses critical global challenges, including climate change, biodiversity loss, and sustainability. These complex topics generate a vast amount of both structured and unstructured data, from remote sensing output to policy documents, guidelines, and scientific literature. Effectively processing and utilizing this information is essential for advancing research and supporting decision-making. Large Language Models (LLMs) have shown remarkable capabilities in natural language understanding an [...]

1182 8080

Open Access Review

Evidence-Based Rapid Review of Clean Cooking: Lessons for Nigeria and Other Developing Economies

Received: 08 December 2024;  Published: 25 July 2025;  doi: 10.21926/aeer.2503027

Abstract

Biomass-fuel use by over 2 billion of the world’s population contributes to their poor respiratory health and climate change. This paper traces the history of clean cooking and explores strategies for its sustained adoption in developing countries, such as Nigeria, drawing on global lessons from past successes and failures. This study employed a rapid review methodology to synthesize evidence and inform decision-making on the adoption of clean cooking. The research was guided by a central question on how to p [...]

1175 8756

Open Access Original Research

Treatment of Contaminated Water Collected from River Getsi Using Enhanced Natural Coagulant Prepared from Chrysophyllum Albidium Seeds

Received: 31 March 2025;  Published: 15 July 2025;  doi: 10.21926/aeer.2503026

Abstract

The high cost of chemical coagulants for water treatment leads most people in rural communities to resort to readily available surface water, which is usually of low quality, exposing them to various waterborne diseases. It is in this light, that research was conducted to assess the effectiveness of a cheap enhanced natural coagulant prepared from Chrysophyllum albidium seeds for the treatment of contaminated water sampled from River Getsi, which serves as a source of potable water for the society. The coagulants s [...]

681 3249

Open Access Original Research

Air Pollution Control Engineering in Urban and Congested Areas

Received: 04 February 2025;  Published: 11 July 2025;  doi: 10.21926/aeer.2503025

Abstract

The study aims to evaluate the progressive increase in energy systems pollutant emissions due to the efficiency loss and continuous deterioration in the energy conversion process. The paper analyzes the GHG, nitrous oxide, sulfur dioxide, and fine particle emissions from vehicles, residential and commercial heating systems, public buildings, health centers, and industrial conglomerates, with the servicing time and degradation level. The analysis applies to various emitting gases or small particle systems, which gen [...]

645 3225

Open Access Review

Comparison of Compressed Air Flow Measurement Techniques for Industrial Energy Efficiency Enhancement

Received: 31 October 2024;  Published: 24 June 2025;  doi: 10.21926/aeer.2502024

Abstract

Across the industrial sector, compressed air is utilized as an easy-to-use and readily accessible tool in a variety of applications. This tool is commonly misunderstood as being more efficient than it is in reality. Air compression is energy intensive and thus both economically and environmentally costly. Compressed air typically only achieves around ~15% efficiency if judged by the energy delivered from the air, meaning approximately 5-6 kWh are wasted for every 1 kWh of useful work performed by compressed air. Du [...]

824 6479

Open Access Original Research

The Intra-Institutional Waste Management in Montevideo Healthcare Centers

Received: 23 September 2024;  Published: 20 May 2025;  doi: 10.21926/aeer.2502023

Abstract

Healthcare Waste (HCW) management is a pressing challenge in Latin America, where insufficient regulatory enforcement, poor segregation practices, and the lack of accurate generation data hinder sustainable waste management. This study presents a methodological proposal for the internal management of HCWs in Healthcare Centers (HCCs) in Uruguay, based on Decree 586/009 and developed through a situational diagnosis conducted at the Hospital de Clínicas "Dr. Manuel Quintela." The diagnosis involved the qualitative an [...]

744 5435

Open Access Review

An Overview of the Hydrocarbon Sector in India for Carbon Capture Scope

Received: 28 November 2024;  Published: 07 May 2025;  doi: 10.21926/aeer.2502022

Abstract

The hydrocarbon sector in India plays a pivotal role in the country's energy landscape, encompassing exploration, production, refining, and distribution activities. This abstract provides a concise overview of the sector's current status, challenges, and prospects. India's hydrocarbon reserves range from conventional to unconventional sources, with significant potential yet to be tapped. However, the sector faces challenges such as declining production from mature fields, technological limitations in ex [...]

903 8256

Open Access Research Article

Analysis of Global Scientific Production on Health Service Waste through Bibliometric and Scientometric Indicators

Received: 19 October 2024;  Published: 27 April 2025;  doi: 10.21926/aeer.2502021

Abstract

Inadequate management of healthcare waste represents a significant challenge to public health and the environment. This study aims to analyze global scientific production on healthcare waste using bibliometric and scientometric indicators, providing a comprehensive overview of research trends and areas of interest. Data from academic databases were used to map the temporal distribution of publications, identify the leading countries, institutions, and researchers involved, and evaluate collaboration networks and jo [...]

705 4000

Open Access Original Research

Utilizing Machine Learning to Map Aquatic Weed Yields for Biochar Production: A Case Study in the Bangweulu Wetlands, Zambia

Received: 26 September 2024;  Published: 17 April 2025;  doi: 10.21926/aeer.2502020

Abstract

Aquatic weeds present significant ecological and socio-economic challenges in the Bangweulu Wetlands of northern Zambia, where their proliferation disrupts aquatic ecosystems, impedes fishing activities, and affects local livelihoods. Despite these challenges, aquatic weeds also offer a unique opportunity for sustainable biochar production, a clean alternative cooking fuel that can alleviate pressure on diminishing forest resources. This study explores the application of machine learning (ML) techniques to estimate [...]

780 4723

Open Access Original Research

Hydrochemical Characteristics of Groundwater in the Mutoshi Deposit Environment, Kolwezi (Lualaba, DR Congo)

Received: 19 September 2024;  Published: 16 April 2025;  doi: 10.21926/aeer.2502019

Abstract

This study examines the hydrochemical characteristics of groundwater in the Mutoshi mining environment in Kolwezi, Democratic Republic of Congo, addressing gaps in understanding the impact of mining on water quality. Despite the DRC's vast water resources, only 26% of the urban population has access to safe drinking water, with the Mutoshi aquifer, providing over a quarter of Kolwezi's drinking water, facing deterioration due to underlying copper and cobalt-rich geological formations. Groundwater and geological sam [...]

755 6595

Open Access Original Research

Assessment of the Main Elements for a Healthcare Waste Management System Using Analytical Hierarchical Process

Received: 16 October 2024;  Published: 10 April 2025;  doi: 10.21926/aeer.2502018

Abstract

When addressing Healthcare Waste Management (HCWM), numerous factors play a crucial role in ensuring its safety and environmentally responsible handling within institutional processes. Recognizing this imperative, this study employed the Analytical Hierarchical Process (AHP) methodology to establish a comprehensive assessment of 10 primary criteria and 66 sub-criteria concerning the governance and operational aspects of Healthcare Waste Management. This evaluation was based on the insights of 14 specialists in the [...]

834 5884

Open Access Original Research

Sustainable Alternatives for Energy Generation and Food Production in Brazil

Received: 23 September 2024;  Published: 07 April 2025;  doi: 10.21926/aeer.2502017

Abstract

Urbanization driven by industrialization and population growth amplifies food consumption and reinforces the need for more fuels and energy. However, the expansion of biofuels can impose risks on long-term food security. This paper examines potential alternative crops for energy generation and food production, including those used by family farmers and their associations, to decentralize energy production and utilization as a crucial pillar of the global energy transition. Cassava, corn, and sugar beet are the chos [...]

1259 7947

Open Access Concept Paper

Enhancing Biodiversity Education and Outreach for Conservation Awareness and Environmental Stewardship

Received: 15 August 2024;  Published: 02 April 2025;  doi: 10.21926/aeer.2502016

Abstract

Biodiversity—the rich variety of life on Earth—is essential for ecosystem stability and resilience, which, in turn, supports human well-being. However, human activities, such as habitat destruction, pollution, overexploitation, and climate change, are placing unprecedented pressures on global biodiversity, emphasizing the need for urgent conservation measures. In response, biodiversity education and outreach initiatives have become pivotal in fostering conservation awareness and action. This paper critically evalua [...]

1496 9988

Open Access Research Article

An Analysis of Thermal Comfort in a School’s Outdoor Space: A Case Study of a Typical School, Dubai, UAE

Received: 29 October 2024;  Published: 01 April 2025;  doi: 10.21926/aeer.2502015

Abstract

Outdoor school spaces are significant, as they provide great opportunities for outdoor exploration, leading to the overall enhancement of a student’s well-being. This paper analyzes the outdoor school spaces in Dubai to optimize them and ensure their thermal comfort. To achieve this aim, using a mixed methodology approach of survey, field observation, workshops and ENVI-met V5.3 software simulation, the existing outdoor spaces were analyzed and then enhanced using several proposed heat mitigation strategies. The im [...]

855 9548

Open Access Original Research

Development of a Life Cycle Sustainability Assessment Framework for Hemp-Based Building Materials in Australia

Received: 18 December 2024;  Published: 27 February 2025;  doi: 10.21926/aeer.2501014

Abstract

The construction industry, a cornerstone of global economic and social progress, is under increasing pressure to adopt sustainable practices due to its significant environmental footprint. Industrial hemp (Cannabis sativa L.) has gained attention as a renewable material for building applications, offering potential reductions in greenhouse gas emissions and resource consumption. However, its broader sustainability performance remains underexplored. This study develops a comprehensive Life Cycle Sustainability Asses [...]

1146 9333

Open Access Review

Wind Turbines for Decarbonization and Energy Transition of Buildings and Urban Areas: A Review

Received: 14 August 2024;  Published: 26 February 2025;  doi: 10.21926/aeer.2501013

Abstract

The recent tendencies of drastic variations of environmental conditions, inundations, severe winds, and gusts besides heavy and unexpected long-duration rains showed the world an image of what could happen if emissions and global warming are not adequately controlled. Implementing new energy solutions as fast as possible is essential to cope with climate change, one of the biggest threats to our survival. These alarming signs intensified research and development efforts to replace fossil-based activities with renew [...]

1282 17676

Open Access Original Research

Physical Education: Equity of Learning and Social Inclusion for Blind Students

Received: 15 July 2024;  Published: 19 February 2025;  doi: 10.21926/aeer.2501012

Abstract

Equity in the educational system is crucial to addressing the needs of all students without distinction, from their initial access to education through to graduation. Achieving equity requires implementing reasonable adjustments to ensure that all students can attend classes, actively participate, and learn effectively. Equity entails transforming inequality into inclusion, enhancing students' well-being and quality of life. Education for all prioritizes equity and quality as fundamental principles of the education [...]

972 6080

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