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Open Access Review

Mechanisms of Origin and Clinical Effects of Multiple Small Supernumerary Marker Chromosomes, Each Derived from a Different Chromosome

Received: 15 November 2016;  Published: 10 February 2017;  doi: 10.21926/obm.genet.1701002

Abstract

Small supernumerary marker chromosomes (sSMCs) are centric chromosome fragments additionally present in an otherwise normal human chromosome set that cannot be characterized by classical cytogenetic techniques alone. The majority of sSMCs are not yet related to a defined clinical phenotype. We compiled from the literature all 78 cases with multiple sSMCs per cell in which the chromosomal origin of the sSMCs has been identified. The number of sSMCs varies from 2 to 7; 64% have 2 sSMCs, 14% have 3 sSMCs, and the freq [...]

1764 11333

Open Access Editorial

Treasure Your Exceptions and Submit These to OBM Genetics

Received: 16 January 2017;  Published: 10 February 2017;  doi: 10.21926/obm.genet.1701001

917 6770

Open Access Original Research

Photocatalytic and Catalytic Methods for Organic Azo Dyes and Paranitrophenol Pollutants Removal Using Green Synthesised Flacourtia indica Silver Nanoparticles

Received: 30 October 2025;  Published: 12 February 2026;  doi: 10.21926/cr.2601004

Abstract

The advancement of photocatalytic nanomaterials has become central to addressing the growing challenge of removing organic pollutants from water systems through sustainable and efficient degradation pathways. In this study, silver nanoparticles were synthesized via a green approach using aqueous extracts derived from five parts of Flacourtia indica, including bark, flower, fruit, seed, and leaves, at 90°C for 45 minutes. UV–VIS spectroscopy (460 nm) confirmed nanoparticle formation, while scanning electron microsco [...]

377 969

Open Access Original Research

Promising Electrocatalytic Systems 2,5-di-Me-Pyrazine-di-N-Oxide - Cyclohexanol - Single-Walled and Multi-Walled Carbon Nanotubes for the Simultaneous Metal-Free Oxidation of Cyclohexanol at Anode and Release of Hydrogen Evolution at Cathode

Received: 07 August 2025;  Published: 26 January 2026;  doi: 10.21926/cr.2601003

Abstract

Electrocatalytic oxidation of organic compound in the absence of noble metals or their oxides as catalysts and using metal-free electrodes is a "green" electrochemical, inexpensive and attractive process for practical use in electrocatalysis, power sources and sensors. The process accompanied by the elimination of protons, is of interest both for obtaining valuable organic compounds at the anode and for the release of hydrogen evolution at the cathode. In this work, the catalytic oxidation of cyclohexanol in the pr [...]

382 929

Open Access Original Research

Valorization of Agro-Industrial Residues into Furfural via Catalytic Pyrolysis

Received: 15 October 2025;  Published: 12 January 2026;  doi: 10.21926/cr.2601002

Abstract

Pyrolysis is a promising technology for converting biomass waste into bio-oil, a liquid product that can serve as feedstock for fuels and high-value chemicals. In this study, bio-oil was produced via catalytic pyrolysis of pear pulp waste, a byproduct from juice and jam manufacturing, using a fixed-bed reactor. Initial non-catalytic experiments were conducted under nitrogen and vacuum atmospheres at temperatures ranging from 300 to 450°C for 15 minutes to evaluate the effect of temperature on bio-oil yield. The res [...]

397 1171

Open Access Editorial

Acknowledgment to Reviewers of Catalysis Research in 2025

Received: 03 January 2026;  Published: 04 January 2026;  doi: 10.21926/cr.2601001

Abstract

The editors of Catalysis Research would like to express their sincere gratitude to the following reviewers for assessing manuscripts in 2025. We greatly appreciate the contribution of expert reviewers, which is crucial to the journal's editorial process. We aim to recognize reviewer contributions through several mechanisms, of which the annual publication of reviewer names is one. Reviewers can download a certificate of recognition directly from our submission system. Additionally, reviewers can sign up to the Web [...]

625 1027

Open Access Original Research

Paranitrophenol and Organic Azo Dye Degradation: Catalytic Power of Terminalia Leaf Silver Nanoparticles

Received: 19 September 2025;  Published: 01 December 2025;  doi: 10.21926/cr.2504010

Abstract

Terminalia species is a widely available plant that can be used to synthesise silver nanoparticles (AgNPs) and harness their catalytic capacity. This experimental design will explore the potential of Terminalia AgNPs in contributing to the degradation process of toxic chemicals generated by industries such as textiles, food, and pharmaceuticals. This research uses four leaf varieties of Terminalia species—T. arjuna, T. bellirica, T. chebula, and T. catappa—to synthesize AgNPs, evaluate their optimal synthesis condi [...]

586 3630

Open Access Original Research

Fabrication of CuO-Decorated Fe2O3 Nanoparticles as Efficient and Durable Electrocatalyst for Oxygen Evolution Reaction

Received: 09 August 2025;  Published: 07 November 2025;  doi: 10.21926/cr.2504009

Abstract

The electrochemical water oxidation application of CuO@Fe2O3 materials as potential catalysts is being reported for the first time. A series of CuO@Fe2O3 with different molar ratios of CuO (5, 7, 10, 12, and 15%) was fabricated through precipitation followed by the impregnation method. Structural and electrochemical studies were carried out by using different analytical platforms, including X-ray diffraction (XRD), Fourier transform infrared spectroscopy (FTIR), scanning electron microscopy (SEM), Energy dispersive [...]

838 2672

Open Access Editorial

The Next Frontier in Photocatalytic Hydrogen Generation

Received: 24 October 2025;  Published: 03 November 2025;  doi: 10.21926/cr.2504008

953 2826

Open Access Editorial

Advances in Photocatalytic Methods for Organic Pollutant Removal

Received: 01 July 2025;  Published: 03 August 2025;  doi: 10.21926/cr.2503007

1355 4439

Open Access Editorial

Catalysis for Biomass Conversion: Pioneering Emission Control and Sustainable Energy Futures

Received: 08 July 2025;  Published: 10 July 2025;  doi: 10.21926/cr.2503006

1245 4850

Open Access Editorial

Catalysis, Meet the Machine: From Models to Meaning

Received: 25 June 2025;  Published: 27 June 2025;  doi: 10.21926/cr.2502005

909 4284

Open Access Review

Lignocellulosic Biomass and Enzymes: Fundamentals, Emerging Technologies, and Applications

Received: 25 January 2025;  Published: 19 June 2025;  doi: 10.21926/cr.2502004

Abstract

Lignocelluloses are complex plant polysaccharides made of lignin, cellulose, and hemicellulose, and products made from these components find immense market potential. They can be effectively valorized to products related to bioenergy, bioplastics, food and nutrition, medication delivery systems, and other elements. Significant sources of lignocellulosic biomass include sugarcane bagasse, corn cob, rice straw, potato haulms, cocoa pods, etc. Enzyme-based valorization processes find immense potential, as they are eco [...]

1320 10408

Open Access Original Research

Soil Treatment from Hazardous Particles Using Designed Nanosensors: A Physical and Chemical Analysis

Received: 11 November 2024;  Published: 06 March 2025;  doi: 10.21926/cr.2501003

Abstract

Being critical to achieving Sustainable Development Goals (SDGs) of the United Nations, strengthening understanding of the properties and processes of soil at national and regional scales is imperative. The target of this research is removing transition metals of Cr, Mn, Fe, Zn, W, Cd from soil due to nanomaterial-based boron nitride nanocage (B5N10-nc). The electromagnetic and thermodynamic attributes of toxic transition metals trapped in B5N10-nc were depicted by materials modeling. It has been studied the behavi [...]

1126 5005

Open Access Original Research

Catalytic Performance of CO:Ni Mixed Oxide Based Catalyst for Green Fuel Synthesis from Biomass Derived Citrullus Colocynthis Oil

Received: 18 September 2024;  Published: 08 January 2025;  doi: 10.21926/cr.2501002

Abstract

This study aimed to synthesize nickel oxide (NiO) and cobalt oxide (Co3O4) based catalysts for synthesizing biodiesel from Citrullus colocynthis oil. Cobalt-nickel mixed oxide catalysts made by co-precipitation technique with different Cobalt to Nickel ratios and named Co:Ni (50:50), Co:Ni (67:33), and Co:Ni (33:67). The Characterization of these synthesized catalysts was performed by XRD and SEM analysis. The transesterification process checked the catalytic activity of these catalysts, and it was found that Co:Ni [...]

2267 9253

Open Access Editorial

Acknowledgment to Reviewers of Catalysis Research in 2024

Received: 02 January 2025;  Published: 02 January 2025;  doi: 10.21926/cr.2501001

Abstract

The editors of Catalysis Research would like to express their sincere gratitude to the following reviewers for assessing manuscripts in 2024. We greatly appreciate the contribution of expert reviewers, which is crucial to the journal's editorial process. We aim to recognize reviewer contributions through several mechanisms, of which the annual publication of reviewer names is one. Reviewers can download a certificate of recognition directly from our submission system. Additionally, reviewers can sign up to the Web [...]

929 3733

Open Access Editorial

MOF-based Heterogeneous Catalysis: A Frontier in Sustainable Chemical Transformations

Received: 02 December 2024;  Published: 05 December 2024;  doi: 10.21926/cr.2404014

1486 8313

Open Access Editorial

Opportunities and Challenges of Molecular Catalysts

Received: 28 November 2024;  Published: 02 December 2024;  doi: 10.21926/cr.2404013

1294 4682

Open Access Editorial

Advanced Catalysis for Green Fuel Production from Biomass and Wastes

Received: 19 August 2024;  Published: 22 August 2024;  doi: 10.21926/cr.2403012

1268 5533

Open Access Review

Exploration of Molybdenum Oxide Compounds-A Review

Received: 17 February 2024;  Published: 09 August 2024;  doi: 10.21926/cr.2403011

Abstract

The evolution of nanomaterials has been critical in modifying materials at the nanoscale for specialized uses. Carbon nanotubes were initially viewed as promising for electronics, but their inability to discriminate between semiconducting and metallic phases led to the creation of quasi-two-dimensional (Q-2D) materials. Molybdenum nanoparticles are utilized as alloy additions in corrosive and high-vacuum environments. Their characteristics differ significantly from those of their bulk counterparts. This review anal [...]

4419 29662

Open Access Original Research

Leaf Mediated Curcuma sp. Silver Nanoparticles as Catalyst - Evaluating Their Antioxidant, Cytotoxicity, Para-Nitrophenol Catalytic and Photocatalytic Activity

Received: 29 April 2024;  Published: 22 July 2024;  doi: 10.21926/cr.2403010

Abstract

Nanotechnology is a fast-rising market in catalytic research; however, the production of eco-friendly nanoparticles remains a significant challenge. In this study, silver nanoparticles (AgNPs) were synthesized from the agro-industrial waste of leaves of C. longa, C. aromatica, C. caesia, C. zedoaria, and C. amada at RT after 24 h, which was confirmed with UV-spectrophotometric evaluation between 320-520 nm. SEM revealed cubic and 30-50 nm AgNPs, while band-gap energy was presented as semi-conductors. Synthesized Ag [...]

1642 17207

Open Access Research Article

Kinetic Model for the Hydrolysis of Olive Oil by Lipase in Absence of Emulsifier

Received: 27 March 2024;  Published: 18 July 2024;  doi: 10.21926/cr.2403009

Abstract

Lipase-catalyzed hydrolysis of olive oil has been studied in the absence of emulsifier. A simple mathematical model to predict the hydrolysis rate is derived from a proposed kinetic mechanism of the reaction. The hydrolytic reaction obeys Michaelis-Menten kinetics with a simultaneous second-order enzyme deactivation. The model predictions closely agree with the experimental results.

1512 9426

Open Access Original Research

Effective Photogeneration of Singlet Oxygen and High Photocatalytic and Antibacterial Activities of Porous Mn-Doped ZnO-ZrO2 Nanocomposites

Received: 06 April 2024;  Published: 03 July 2024;  doi: 10.21926/cr.2403008

Abstract

Disperse porous Mn-doped ZnO-ZrO2 nanocomposites were prepared using the facile polymer-salt method. The effect of Mn content on the crystal structure, composite morphologies, their ability to photogenate the singlet oxygen, luminescence properties, and bactericidal activities were studied. The crystal structure and morphology of these materials were investigated using XRD and SEM analysis. It was found that obtained nanocomposites consist of small (~9 nm) hexagonal ZnO and fine ZrO2 crystals and the embedding of M [...]

1087 7075

Open Access Original Research

Determination of Reflectance Spectra and Colorimetry of Titanium and Tungsten Oxides Obtained by Microwave-assisted Hydrothermal Synthesis

Received: 04 February 2024;  Published: 01 July 2024;  doi: 10.21926/cr.2403007

Abstract

Sustainability has driven the use of heterogeneous photocatalysis as one of the primary methods for environmental decontamination, reduction, degradation, remediation, or transformation of polluting chemical residues and purification treatment of effluents and wastewater. TiO2 is the most commonly used semiconductor in heterogeneous photocatalysis. It acquires relevance, as it has favorable properties, such as non-toxicity, stability in a wide range of pH, economic viability, etc., which encourage its application a [...]

1135 5968

Open Access Review

llmenite and Biomass Composite Nanomaterials - A Review

Received: 10 April 2024;  Published: 13 June 2024;  doi: 10.21926/cr.2402006

Abstract

Ilmenite is a mineral whose crystallinity can be altered by chemical treatment, producing TiO2 and iron and titanium-based metal nanocomposites, which are applicable mainly for photocatalysis. Porous and crystalline biomass-derived carbon materials include graphene oxide, reduced graphene oxide, graphitic carbon nitride, catalytically graphitized sucrose and chitosan, and activated carbon. Ilmenite-based metal oxides coupled with biomass-based carbon materials are effective in environmental remediation, especially [...]

1458 8820

Open Access Original Research

A Remarkable Pt Doped CNT Catalyst as a Double Functional Material: Its Application for Hydrogen Production and Supercapacitor

Received: 25 December 2023;  Published: 15 May 2024;  doi: 10.21926/cr.2402005

Abstract

In this study, by producing bifunctional material, hydrolysis, and supercapacitor applications were investigated. The carbon nanotube-supported Pt catalyst was prepared using the sodium borohydride (NaBH4) reduction. Surface characterization of the synthesized Pt/CNT catalyst was performed using scanning electron microscopy-energy dıstrıbutıon X-ray spectrometer (SEM-EDX), X-ray diffraction (XRD), and transmission electron microscopy (TEM). Hydrolysis experiments were performed after deciding on the appropriate ato [...]

1368 7345

Open Access Editorial

Solid Catalysts – New Perspectives and Applications

Received: 31 March 2024;  Published: 09 April 2024;  doi: 10.21926/cr.2402004

1335 7242

Open Access Original Research

The Effect of SnO2 and Rh on Pt Nanowire Catalysts for Ethanol Oxidation

Received: 24 November 2023;  Published: 11 March 2024;  doi: 10.21926/cr.2401003

Abstract

In this study, we synthesized Pt-Rh nanowires (NWs) through chemical reduction of metallic precursors using formic acid at room temperature, excluding the use of surfactants, templates, or stabilizing agents. These NWs were supported on two substrates: carbon (Vulcan XC-72R) and carbon modified with tin oxide (SnO2) via the sol-gel method (10 wt.% SnO2). We explored the electroactivity of Pt/SnO2/C, Pt-Rh/C, Pt-Rh/SnO2(commercial)/C (commercial SnO2), and Pt-Rh/SnO2/C NWs toward electrochemical oxidation of ethanol [...]

1902 13094

Open Access Research Article

Synthesis of NaA Zeolite: Conventional Route and Green Route

Received: 24 October 2023;  Published: 28 January 2024;  doi: 10.21926/cr.2401002

Abstract

The research describes a sustainable approach for the synthesis of zeolite NaA using kaolin as an alternative source of silica. The main objective of this research was to prepare NaA zeolite using metakaolin derived from kaolin from the state of Rio Grande do Norte, Brazil, as an alternative source of silica, reducing the production cost and evaluating its thermal stability. In addition, a study of the thermal stability of the zeolite and cost estimates for zeolite production were carried out. Traditional methods o [...]

2012 12601

Open Access Editorial

Acknowledgement to Reviewers of Catalysis Research in 2023

Received: 03 January 2024;  Published: 04 January 2024;  doi: 10.21926/cr.2401001

Abstract

The editors of Catalysis Research would like to express their sincere gratitude to the following reviewers for assessing manuscripts in 2023. We greatly appreciate the contribution of expert reviewers, which is crucial to the journal’s editorial process. We aim to recognize reviewer contributions through several mechanisms, of which the annual publication of reviewer names is one. Reviewers can download a certificate of recognition directly from our submission system. Additionally, reviewers can sign up to th [...]

829 5100

Open Access Research Article

NaY Zeolite Synthesis from Vermiculite and Modification with Surfactant

Received: 24 October 2023;  Published: 26 December 2023;  doi: 10.21926/cr.2304031

Abstract

This work focuses on preparing NaY zeolite using alternative sources of silica and modifying the zeolite with the surfactant cetyltrimethylammonium bromide. Two different hydrothermal synthesis routes were employed: the conventional method using sodium silicate as the silica source, and the other is a sustainable approach using vermiculite clay as the silica source. In traditional zeolite synthesis, sodium silicate is often used as the source of silica. However, . The vermiculite was subjected to an acid treatment, [...]

1861 10563

Open Access Research Article

Synthesis of SAPO-34 Zeolite Membrane: Influence of Sources of Silica

Received: 03 October 2023;  Published: 11 December 2023;  doi: 10.21926/cr.2304030

Abstract

The research described the production and characterization of various materials, particularly alpha-alumina ceramic supports, zeolite SAPO-34, and zeolite membranes. Ceramic supports were manufactured through dry uniaxial compaction. Sintering of the supports was carried out at 1300°C for 2 h. SAPO-34 zeolites and zeolite membranes were synthesized through a hydrothermal process involving two steps: a first step at 38°C for 24 h and a second step at 200°C for 24 h. The research aimed to determine how different sili [...]

1633 11525

Open Access Original Research

In Water High Yield and Selectivity of CH4 and H2 Production from CO2 Using UVC Light and a SiO2-surface-modified TiO2 Photocatalysts

Received: 25 August 2023;  Published: 05 December 2023;  doi: 10.21926/cr.2304029

Abstract

To improve CH4 and H2 formation from CO2 photoreduction using non-organic, non-laborious, and inexpensive photocatalysts, we have prepared two surface-silicate-modified TiO2 catalysts: P25-SiO2 and AmTiO2-SiO2 (amorphous TiO2) to be tested in water and using UV light. The last catalyst produces more CH4 and H2 in water than P25 (3:1 TiO2 anatase: rutile) under UV light irradiation of HCO3- and CO2; am-TiO2-SiO2 at pH = 7, produces 8 times more CH4 and H2 than P25 with selectivity at the reactor headspace of 30% and [...]

1900 8909

Open Access Research Article

Nano Metal Oxide Frameworks (NOF): Development of New Heterogeneous Catalyst for the Synthesis of Furan Derivatives from Glucose

Received: 01 June 2023;  Published: 21 November 2023;  doi: 10.21926/cr.2304028

Abstract

A surface modification approach has prepared a nanostructured organic framework connecting two metal oxide NPs. The surface modifier attached two metal oxide NPs via molecular interaction to generate modular structures of fiber, rod, or sponge materials. Thus, obtained hybrid systems have been confirmed through FT-IR, TGA, PXRD, and SEM. Metal oxides such as Fe3O4 and MgO generated mixed materials via the surface modification approach. Thus, obtained materials have been successfully used to dehydrate biomass-derive [...]

1934 8803

Open Access Research Article

Impact of Pt-Ni Nanoparticle Architecture on Electrocatalytic Oxidation Reaction in Fuel Cells

Received: 04 September 2023;  Published: 16 November 2023;  doi: 10.21926/cr.2304027

Abstract

This paper investigates how the aggregation of bimetallic nanoparticles (NPs) influences the electronic condition of the surface adsorption site and, hence, the performance of materials during the electrooxidation of fuels in an alkaline medium. First, we synthesized Pt-Ni NPs in three configurations: ordered intermetallic, ordinary alloy, and core-shell. The NPs contained Pt and Ni close to a 1:1 Pt/Ni atomic ratio. They had similar particle sizes, which allowed us to evaluate their performance without the influen [...]

1594 8326

Open Access Review

Enzymes in Poly(Butylene-Succinate) Industry: An Overview on Synthesis Routes and Post-Processing Strategies

Received: 16 June 2023;  Published: 08 November 2023;  doi: 10.21926/cr.2304026

Abstract

This paper will present some sectors in which enzymes can replace traditional catalysts in poly(butylene-succinate) industry, emphasizing the green chemistry aspects associated with these newer strategies.

1675 13486

Open Access Original Research

Tungstophosphate Intercalated ZnAl Layered Double Hydroxide for Adsorptive and Visible Light Driven Photocatalytic Decolourisation of Organic Dyes

Received: 21 December 2022;  Published: 13 October 2023;  doi: 10.21926/cr.2304025

Abstract

Tungstophosphate (PW12O403-) intercalated ZnAl-Layered double hydroxide (ZnAl-PW12) was successfully synthesized through the rehydration of calcined LDH. Chemical analyses and characterizations by powder XRD, FT-IR, and Diffuse reflectance UV-Vis spectra confirmed the intercalation of PW12O403- ions equivalent to ~80% of the residual positive charge in the brucite layer. The efficiency of ZnAl-PW12 for decolourisation of four structurally different cationic/anionic dyes through simultaneous adsorption and photocata [...]

1351 8503

Open Access Short Review

Perovskite Oxide Thermoelectric Module - A Way Forward

Received: 27 July 2023;  Published: 11 October 2023;  doi: 10.21926/cr.2304024

Abstract

In the era of renewable and sustainable energy, perovskite materials remain pioneers as energy harvesting materials, be it thermoelectric waste heat harvesting or photovoltaic solar cell application. Oxide perovskite material is an emerging thermoelectric material in solving energy shortage issues through waste heat recovery. The chemical and structural stabilities, oxidation resistance, and cost-effective and straightforward manufacturing process are a few advantages of the oxide-based thermoelectric materials. Th [...]

2077 10987

Open Access Editorial

Nb2O5: Percentage Effect of T/H Phase and Evaluation of Catalytic Activity, a Preliminary Study

Received: 18 September 2023;  Published: 22 September 2023;  doi: 10.21926/cr.2303023

Abstract

Due to its similar characteristics to titanium, niobium has become an attractive alternative in photocatalytic processes. Research indicates that titania has an optimal percentage of phases resulting in a commercial catalyst, P25, that contains more than 70% anatase with a minor amount of rutile and a small amount of amorphous phase. On the other hand, for Nb2O5, percentage optimization was little explored in the literature, which consists of studying the phases obtained via heat treatment individually and in diffe [...]

1569 8053

Open Access Original Research

Enhancing Kerosene Selectivity of Fischer-Tropsch Synthesis by Periodical Pore Drainage Via Hydrogenolysis

Received: 27 June 2023;  Published: 12 September 2023;  doi: 10.21926/cr.2303022

Abstract

Accumulation of wax inside the catalyst pores during transient cobalt-catalyzed Fischer-Tropsch synthesis (FTS) leads to unfavorable product distribution and low activity by imposing internal mass transfer limitations. The condensation of paraffin severely changes the apparent product stream that actually leaves the reactor before the catalyst pores are filled completely and the steady state is reached. Thus, the product distribution of the transient FTS is less complex than expected in comparison to the steady-sta [...]

1870 13608

Open Access Original Research

Research and Application of Modified ZSM-5 for the Process of Alkylation of Oil Distillate Fractions

Received: 20 April 2023;  Published: 10 August 2023;  doi: 10.21926/cr.2303021

Abstract

In the oil distillate fraction alkylation process, a modified Zr zeolite ZSM-5 was obtained and studied. The modification was executed using a method that impregnated ZSM-5 with a 5% solution of ZrOCl2∙6H2O. X-ray diffraction studies were conducted on zeolite ZSM-5, zirconyl chloride modifier ZrOCl2∙6H2O, and modified zeolite ZSM-5-ZrO2, which was calcined at temperatures of 200, 400, and 550°C. The results revealed that the phase composition of modified ZSM-5-ZrO2 zeolite samples varied depending on the calcinatio [...]

1131 7675

Open Access Review

Recent Development of Photocatalytic Application Towards Wastewater Treatment

Received: 15 April 2023;  Published: 05 July 2023;  doi: 10.21926/cr.2303020

Abstract

With increasing population levels and rapidly growing industries worldwide, the purification of water contaminated with different impurities is one of the biggest challenges we face in recent times. Photocatalysis holds great potential as an efficient mineralization process to remove the foreign matter present in wastewater. Rapid advancement in innovative materials development has made photocatalysis the frontrunner among different water treatment methods. Our main priority lies in different strategic approaches t [...]

2334 17355

Open Access Research Article

Production and Characterization of Carboxymethylcellulase by Submerged Fermentation of Moniliophthora perniciosa

Received: 24 December 2022;  Published: 12 June 2023;  doi: 10.21926/cr.2302019

Abstract

Microorganisms that are capable of degrading lignocellulolytic materials can produce extracellular cellulase complexes. Microorganisms are an excellent alternative for the production of cellulolytic complex, since these sources have a high power of multiplication. In this work, we researched the production by the fungus Moniliophthora perniciosa. The production and pH and temperature optimum optimization were studied by Response surface methodology and carboxymethylcellulase (CMCase) characterization. Thermal stabi [...]

1151 7502

Open Access Research Article

Influence of Bifunctional PtZn/SiO2 and H-ZSM-5 Catalyst on the Rates and Selectivity of Propene Aromatization

Received: 28 March 2023;  Published: 06 June 2023;  doi: 10.21926/cr.2302018

Abstract

Previous studies on the conversion of olefins to aromatics with bifunctional Ga- or Zn-ZSM-5 catalysts have concluded that benzene, toluene, and xylenes (BTX) yields are significantly higher than for ZSM-5 alone. These results were attributed to the higher aromatic dehydrogenation rate of Ga or Zn. In this study, a highly active, bifunctional PtZn/SiO2 (1.3 wt% Pt, 2.6 wt% Zn) with H-ZSM-5 (Si/Al = 40) catalyst is investigated for propene aromatization at 723 K and 823 K. At low to moderate propene conversions, in [...]

1320 9729

Open Access Original Research

Synthesis and Characterization of MCM-41 Nanomaterials Containing Titanium and Application for Catalytic Oxidation of BTEX

Received: 17 August 2022;  Published: 30 May 2023;  doi: 10.21926/cr.2302017

Abstract

The TiO2/MCM-41 nanomaterials were synthesized by impregnation with an excess solvent with different percentages of titanium dioxide. They were used for catalytic degradation of Benzene Toluene Ethylbenzene and Xylenes (BTEX) in the presence of hydrogen peroxide in aqueous media. The obtained materials were characterized by X-ray Diffraction, nitrogen adsorption-desorption using the BET method and Fourier Transform Infrared Spectroscopy. The nanostructured phase of the hexagonal ordered materials was obtained even [...]

1757 10349

Open Access Research Article

Obtaining TiO2 Nanostructures by Electrospinning and Analysis of Absorbance in the UVA Spectrum for Photocatalytic Application

Received: 14 December 2022;  Published: 17 April 2023;  doi: 10.21926/cr.2302016

Abstract

The synthesis of fibers by electrospinning allows for obtaining nanostructures of one-dimensional materials with good flexibility, optical and catalytic properties, high surface area and porosity. They can be used in applications such as: catalysts, solar cells, fuel cells, membranes, and hydrogen batteries, among others. Here we emphasize that few reports in the literature describe the existing synergism between the optical and photocatalytic properties of TiO2, and the influence of this synergism on the formation [...]

1033 11564

Open Access Original Research

Organic Structure-Directing Agent Free Synthesis of Mordenite with Seeds, Used as A Support for Mo Catalysts in the Transesterification of Soybean Oil

Received: 20 December 2022;  Published: 07 April 2023;  doi: 10.21926/cr.2302015

Abstract

This work prepared mordenite using seeds and without organic structure-directing agents (OSDAs). The Mo/Mordenite was prepared through wet impregnation and the catalysts’ performance was checked for transesterification of soybean oil with methanol. The mordenite zeolite was prepared through hydrothermal crystallization under static conditions with a molar composition of 6Na2O:Al2O3:30SiO2:780H2O. The catalyst samples were characterized crystallinity through X-ray diffraction, elemental composition by X-ray fluoresc [...]

1248 9302

Open Access Original Research

Spectrophotometric and Spectrofluorimetric Quantification of Urea via Silver Nanoparticles Prepared by Wet Chemical Method

Received: 09 November 2022;  Published: 15 March 2023;  doi: 10.21926/cr.2301014

Abstract

Silver nanoparticles have been utilized in an easy, sensitive, and effective approach through spectrophotometry and spectrofluorimetry to quantify urea in water samples. Here, 1,3-di-(1H-imidazole-1-yl) -2-propanol (DIPO) was employed to stabilize Ag NPs produced from the reduction of aqueous silver nitrate by sodium borohydride (NaBH4). Beer-Lambert's law was applied for determination using the complexation of Ag NPs with urea molecules. The results show urea can be assessed concurrently with good results and perc [...]

1854 13970

Open Access Original Research

Cost-Effective Biodiesel Synthesis from Waste Marble Powder as A Green Heterogeneous Catalyst Using Pongamia Pinnata Oil

Received: 08 December 2022;  Published: 13 March 2023;  doi: 10.21926/cr.2301013

Abstract

Waste marble powder (WMP) is Investigated for developing heterogeneous catalysts by calcination method and used in biodiesel synthesis by esterification-transesterification process from Pongamia Pinnata oil. Hammet indicators, Fourier transform infrared (FT-IR), Thermogravimetric analysis, and X-ray powder diffraction (XRD) techniques were also studied for the characterization of developed catalyst from waste marble powder (WMP). The conversion of calcium carbonate to calcium oxide in marble powder was found at 800 [...]

1594 10099

Open Access Original Research

Sustainable Synthesis of Zeolitic Imidazolate Framework-8 Nanoparticles and Application in the Adsorption of the Drug Chlorhexidine

Received: 06 December 2022;  Published: 13 March 2023;  doi: 10.21926/cr.2301012

Abstract

In an attempt to synthesize nanomaterial concerning chemistry, the sustainable synthesis of Zeolitic Imidazolate Framework-8 (ZIF-8) nanoparticles by a low-cost approach through the recycling of waste mother liquors was explored and then indicated the potential to remove chlorhexidine (CHLX) from an aqueous solution. ZIF-8 was produced under solvothermal reaction at 25°C and characterized by Fourier Transform Infrared Spectroscopy, X-ray diffraction, adsorption/desorption of N2, dynamic light scattering and con [...]

2387 16365

Open Access Research Article

Morpholine-Based Novel Ionic Liquid for Synthesis and Characterization of Triazolidinethiones and Their Biological Properties

Received: 03 December 2022;  Published: 12 March 2023;  doi: 10.21926/cr.2301011

Abstract

Keeping the green chemistry approach in mind we have synthesized a novel morpholine-based ionic liquid [NBMMorph]+Br-. The structure of Ionic liquid was confirmed by spectral techniques viz. IR, 1H NMR, and 13C NMR, analysis. The synthesized novel IL [NBMMorph]+Br- was utilized to prepare 1,2,4-triazolidine-3-thiones of biological significance. The [NBMMorph]+Br- IL shows excellent catalytic activity, and a simple filtration technique can separate the thiazolidinedione products. The structure of the synthesized com [...]

1864 11223

Open Access Original Research

Adsorption of Rhodamine-B (RhB) and Regeneration of MCM-41 Mesoporous Silica

Received: 01 November 2022;  Published: 01 March 2023;  doi: 10.21926/cr.2301010

Abstract

Rhodamine (RhB) adsorption was carried out on MCM-41 and MCM-41 calcined. The effect of parameters such as pH was investigated. The reusability potential of MCM-41 was also established and the mechanism of RhB adsorption was discussed. MCM-41 was synthesized and calcined, with all samples characterized by X-Ray Diffractometry, X-ray Fluorescence by Dispersive Energy, Infrared Spectroscopy, Scanning Electron Microscopy, and Thermogravimetric analysis. The results of the characterization techniques performed confirme [...]

1556 11570

Open Access Original Research

Methanol Synthesis Catalyst Waste as the Principal Component of New Sustainable Cementless Concrete

Received: 08 December 2022;  Published: 27 February 2023;  doi: 10.21926/cr.2301009

Abstract

Methanol synthesis catalyst (MSC) waste was applied as the principal component (till 70 wt.%) of sustainable ceramics in composites with bauxite processing waste (RM), and waste foundry sand (FS). The results of the initial components' chemical interaction studies by a complex of methods (XRD, SEM/EDS/mapping, AAS and LAMMA) during heating demonstrated the synthesis of amorphous glasslike new formation, their filling of pores and compaction of the ceramic’s structure. In this case, a strong chemical and mechanical [...]

1226 8905

Open Access Research Article

Enzymatic Hydrolysis of Meat Waste for a Circular Economy

Received: 30 December 2022;  Published: 16 February 2023;  doi: 10.21926/cr.2301008

Abstract

This work demonstrates the possibility of implementing a technology that allows profitable value to be drawn from the meat waste from retail stores. Protein hydrolysate, collagen and fatty acids were recovered from meat waste through enzymatic hydrolysis using a mixture of enzymes: a protease (Alcalase) and a lipase (Resinase). Enzymatic hydrolysis was studied by response surface methodology (RMS). Four independent variables were used to study the response variables. The analysis showed that all factors including p [...]

1712 11313

Open Access Original Research

Zn(OCOCH3)2·2H2O Catalysed Efficient Preparation of 2-Phenyl-4-Arylmethylidene-5-Oxazolinones under Ultrasonic Condition

Received: 30 September 2022;  Published: 15 February 2023;  doi: 10.21926/cr.2301007

Abstract

2-Phenyl-4-arylmethylidene-5-oxazolinones were synthesized in very high yield by subjecting a mixture of an aryl aldehyde/heterocyclic aldehyde/cinnamaldehyde and hippuric acid in anhydrous acetic anhydride and catalytic Zn(OCOCH3)2·2H2O to ultrasonication at 35 KHz for 4 to 8 min. This method has many advantages: use of a green catalyst; yields are high, involves easy workup procedure, is energy efficient and economically feasible.

1505 8274

Open Access Research Article

The Effects of Ge Substrate Surface States and Au Catalyst Layer Thickness on the Growth of Different GexOy Nanomaterials and Nanocrystals Configurations Using Vapor-Liquid-Solid Method with two Steps Temperature Mode

Received: 01 September 2022;  Published: 31 January 2023;  doi: 10.21926/cr.2301006

Abstract

Recently the GexOy nanomaterials have been studying intensively due to their interesting electronic materials, which have many particular properties and applications in nanotechnology and nano-devices fabrication. Much work has been done on many different synthesis methods and their properties of Ge and GexOy nanomaterials. However, the effects of the different Ge substrate surface states and Au catalyst layer thicknesses on the formation of different forms/morphologies of nanomaterials (nanowires, nanorods, nanopa [...]

1127 9282

Open Access Original Research

Pd-Ni-B/C Nanocatalysts for Electrochemical Oxidation of Ethanol in Alkaline Media

Received: 06 September 2022;  Published: 19 January 2023;  doi: 10.21926/cr.2301005

Abstract

This paper describes the synthesis of Pd0.70-Nix-By nanoparticles (x:y = 0.30:0, 0:0.30, 0.25:0.05, 0.20:0.10, 0.15:0.15, and 0.10:0.20) supported on carbon Vulcan XC-72 R by the chemical reduction method using ethylene glycol as a reducing agent for the study of the electrochemical oxidation of ethanol in alkaline media. Neither surfactants nor templates were used during the syntheses. The catalysts were physically characterized by transmission electron microscopy that showed the formation of nanoparticles with di [...]

1775 10773

Open Access Original Research

Fungal Laccase-Mediated Enhancement of the Bioactivity of Green Algae Extracts

Received: 01 December 2022;  Published: 19 January 2023;  doi: 10.21926/cr.2301004

Abstract

Biomass derived from green marine macroalgae Ulva sp. is considered a rich source of bioactive compounds. In the present study, we demonstrate the increased bioactivity of a phenolic-rich extract derived from green marine macroalgae Ulva intestinalis after its treatment with fungal laccases from Trametes versicolor and Agaricus bisporus. The phenolic composition of the extract, before and after its enzymatic treatment, was determined through several analytical methods. Furthermore, the antioxidant, enzyme-inhibitor [...]

2050 11859

Open Access Editorial

Acknowledgement to Reviewers of Catalysis Research in 2022

Received: 04 January 2023;  Published: 04 January 2023;  doi: 10.21926/cr.2301003

Abstract

The editors of Catalysis Research would like to express their sincere gratitude to the following reviewers for assessing manuscripts in 2022. We greatly appreciate the contribution of expert reviewers, which is crucial to the journal’s editorial process. We aim to recognize reviewer contributions through several mechanisms, of which the annual publication of reviewer names is one. Reviewers receive a voucher entitling them to a discount on their next LIDSEN publication and can download a certificate of recogn [...]

799 5380

Open Access Research Article

Iron Doped Titania/Polyaniline Composite: An Efficient Electrocatalyst for Hydrogen Evolution Reaction in Acidic Medium

Received: 15 September 2022;  Published: 04 January 2023;  doi: 10.21926/cr.2301002

Abstract

The development of noble metal-free catalyst for hydrogen evolution reaction (HER) is the primary challenge in fuel production to replace fossil fuels. Here, we have synthesized Fe-doped TiO2/PANI nanocomposite via facile in situ polymerization method and studied its electrocatalytic activity towards HER. The composite catalyzes HER efficiently with an overpotential value of -180 mV vs. RHE in 0.5 M H2SO4 solution to achieve the current density of 10 mA cm-2 and also possesses unique stability of 8 h. However, a un [...]

1504 9096

Open Access Research Article

Enhancement of Fischer-Tropsch Synthesis by Periodical Draining of the Wax-Filled Pores of a Cobalt Catalyst by Hydrogenolysis

Received: 27 September 2022;  Published: 03 January 2023;  doi: 10.21926/cr.2301001

Abstract

Fischer-Tropsch reactors operated in a steady state suffer from a low pore effectiveness factor and a high methane selectivity caused by internal mass transfer limitations due to the accumulation of long-chain hydrocarbons inside the catalyst pores. Therefore, an alternating process switching between Fischer-Tropsch synthesis (FTS) and drainage of the pores by hydrogenolysis is proposed. The periodical cracking of the accumulated waxes within the (partially) filled pores, realized by a switch from syngas (H2, CO) t [...]

2131 15369

Open Access Research Article

Ethanol Oxidation on Gold Nanowire Containing Oxygen Impurities: A Study by Ab Initio Molecular Dynamics Simulations

Received: 10 October 2022;  Published: 14 December 2022;  doi: 10.21926/cr.2204043

Abstract

Linear atomic chain (LAC) gold nanowires (Au-NWs) containing oxygen impurities are materials that could be used as supports to stimulate chemical reactions. Its peculiar structural characteristics, such as abnormal Au-Au bonds, make it interesting to explore the chemical reactions of this material at a theoretical level. This work investigated the chemical reaction of ethanol supported on Au-NW containing two oxygen impurities. Using ab initio molecular dynamics simulations, it was shown that the presence of oxygen [...]

1792 8675

Open Access Original Research

Fabrication and Catalytic Property of an Ordered Terpyridine Pd(II)/Ni(II) Catalytic Monolayer for Suzuki Coupling Reactions

Received: 21 September 2022;  Published: 02 December 2022;  doi: 10.21926/cr.2204042

Abstract

Fabrication, arrangement, and controllable composition of ordered organometallic films are critical for designing a highly active catalyst and investigating the catalytic mechanism. In this paper, an organometallic terpyridine Pd(II)/Ni(II) monolayer linked on the silicon substrate surface (denoted as Si-Tpy-Pd1/Ni1) was prepared and characterized using water contact angle, ultraviolet spectra, X-ray diffraction, scanning electron microscopy, and X-ray photoelectron microscopy. Si-Tpy-Pd1/Ni1 exhibited high catalyt [...]

1079 7693

Open Access Communication

Biocatalyzed Hydrolysis of Residual Oils and Proteins from Flax and Camelina Oilseed Press Cakes Using Lipase and Protease

Received: 14 September 2022;  Published: 17 November 2022;  doi: 10.21926/cr.2204041

Abstract

In this study, a PoC (Proof of Concept) of a possible biomass valorization of flax and camelina oilseed press cakes was presented. Biocatalyzed hydrolysis of residual oils and proteins extracted from these wastes was studied. The biotransformation of oils was performed using commercial immobilized lipases, including Amano PS, Amano AK, and Candida Antarctica Lipase B (CALB). Acylglycerols were partially or fully hydrolyzed using Amano PS and AK. Triglycerides were not hydrolyzed by CALB, which behaved differently. [...]

1413 7600

Open Access Research Article

Effect of Different Additives on the Structure and Activity of β-Galactosidase Immobilized on a Concanavalin A–Modified Silica-Coated Titanium Dioxide Nanocomposite

Received: 06 August 2022;  Published: 17 November 2022;  doi: 10.21926/cr.2204040

Abstract

Interpreting the relationship between the activity and structure of β-galactosidase is necessary to perceive the impact of the enzyme’s conformation on its catalysis. The current study thoroughly explains the effects of additives such as ethylenediaminetetraacetic acid (EDTA), sodium dodecyl sulfate (SDS), dithiothreitol (DTT), and urea on β-galactosidase activity and structure. β-Galactosidase activity was determined at various ionic strengths and temperatures as a function of time. Structural [...]

1563 9593

Open Access Original Research

Enhanced Photocatalytic Degradation of p-Nitrophenol and Phenol Red Through Synergistic Effects of a CeO2-TiO2 Nanocomposite

Received: 24 July 2022;  Published: 03 November 2022;  doi: 10.21926/cr.2204039

Abstract

Organic compounds are one of the most severe pollutants occurring in the environment. Hence, it is important to remove these compounds from the environment through remediation processes such as photocatalysis. The present study investigated the photocatalytic degradation of p-nitrophenol (NP) and phenol red (PR) using a cerium oxide-titanium oxide nanocomposite (CeO2-TiO2nc) under UV light. CeO2-TiO2nc was synthesized using the co-precipitation method. An X-ray diffraction (XRD) analysis confirmed the phase purity [...]

2322 11135

Open Access Original Research

Thermokinetic and Thermodynamic Parameters for Catalytic Pyrolysis of Medium Density Fiber over Ni/Beta Zeolite

Received: 31 August 2022;  Published: 02 November 2022;  doi: 10.21926/cr.2204038

Abstract

Catalytic pyrolysis is an attractive alternative for converting biomass into energy and chemicals to replace fossil sources. This has encouraged the search for efficient catalysts that can directly remove oxygenated products during pyrolysis, since they are the main problem in the processing and use of the products obtained. The catalytic and non-catalytic pyrolysis of medium density fiber (MDF) over beta zeolite-supported nickel (3 and 5%) was performed using the biomass/catalyst of 1.0/0.2 ratio. The thermokineti [...]

1946 10594

Open Access Original Research

The Effect of Oxygen-containing Additives in Feedstock on the Performance of the Catalytic Cracking Process

Received: 28 July 2022;  Published: 26 October 2022;  doi: 10.21926/cr.2204037

Abstract

In this study, we found that adding catalytic cracking feedstock, vacuum gas oil, and naphthenic acids in the amount of 0.005–0.0075% vol. increased the liquid target fractions, i.e., gasoline and light gas oil. The decrease in the yield of hydrocarbon gas at a practically constant degree of conversion of the raw material indicated a small proportion of the reactions of re-cracking of the resulting products. This also indicated the resource-saving nature of the process, allowing a larger amount of gasoline fraction [...]

1253 7416

Open Access Research Article

Short Hydroacylation-Based Synthesis of Four Aryl-3-hydroxypropanones, Predictable Biomass-Derived C9 Platform Molecules

Received: 22 July 2022;  Published: 26 October 2022;  doi: 10.21926/cr.2204036

Abstract

A two-step protocol for the synthesis of aryl-3-hydroxypropanones, which were regarded as lignin degradation products, was proposed herein. This protocol provided a more rapid and easier access to aryl-3-hydroxypropanones, and aryl-3-hydroxypropanones were expected to be ideal platform molecules for the synthesis of more complex value-added targets.

1655 8565

Open Access Original Research

Effect of ZSM-5 Particle Size and Framework Silica-to-Alumina Ratio on Hexane Aromatization

Received: 13 August 2022;  Published: 17 October 2022;  doi: 10.21926/cr.2204035

Abstract

Parent ZSM-5 and Ga-modified ZSM-5 catalysts with different Si/Al ratios and particle sizes were prepared. The physicochemical properties of the prepared catalysts were investigated by performing X-ray powder diffraction analysis, BET surface area analysis, and NH3-TPD analysis. The performance of the aromatization reaction of the prepared catalysts was evaluated with 1-hexane as a model compound. The zeolite catalysts with a low SiO2/Al2O3 ratio possessed better activity than those with a high SiO2/Al2O3 ratio. Ga [...]

2212 14811

Open Access Research Article

Kinetic Modeling of the Esterification of Oleic Acid and Methanol in Conventional and Adsorptive Reaction Systems

Received: 23 August 2022;  Published: 17 October 2022;  doi: 10.21926/cr.2204034

Abstract

Biodiesel is derived from renewable vegetable or animal sources and is either used as a standalone fuel or blended with oil-based diesel. The kinetic mechanism of the esterification of oleic acid was investigated in a conventional batch reactor and a batch reactor coupled to a water adsorption system. The esterification was performed with oleic acid and methanol at different temperatures (70 to 110 °C) and alcohol-to-oleic acid molar ratios (3:1 to 9:1), using sulfuric acid as a catalyst. A kinetic model was constr [...]

4203 20693

Open Access Review

Perovskite Solar Cells: Assessment of the Materials, Efficiency, and Stability

Received: 14 August 2022;  Published: 14 October 2022;  doi: 10.21926/cr.2204033

Abstract

Solar cells based on organic-inorganic lead halide perovskites are popular in the photovoltaic community due to their high efficiency, low cost, and solution processability. Understanding the fundamentals of metal halide perovskite and its interfaces is extremely important for achieving high-quality materials and developing efficient devices using these materials with the necessary properties. Various methodologies have been used to evaluate the excellent optoelectronic properties, efficiency, and stability of PSCs [...]

4621 35599

Open Access Original Research

3D Printed Polylactic Acid (PLA) Well Plates for Enzyme Inhibition Studies: The Case of Pancreatic Lipase

Received: 31 July 2022;  Published: 08 October 2022;  doi: 10.21926/cr.2204032

Abstract

3D printed PLA has already been demonstrated for several biotechnological applications, including enzymes immobilization. The prerequisites for an efficient screening assay include using small volumes of reagents, low cost, and rapid screening of large numbers of compounds and extracts. Hence, assays based on microtiter plates are predominant. Thus, designing and fabricating scaffolds on a similar scale, which could serve as immobilization carriers, and their recruitment in inhibitors screening studies is of great [...]

1475 9081

Open Access Original Research

Catalytic Co-gasification of Lignites Blended with a Forest Residue under the Carbon Dioxide Stream

Received: 24 May 2022;  Published: 29 September 2022;  doi: 10.21926/cr.2203031

Abstract

The present study investigated the co-gasification of two different lignites blended with the forest residue collected from the land restoration activity sites of open-pit mines located in the region of the Ptolemais basin in North Greece performed under the carbon dioxide stream. All samples were devolatilized in a fixed bed unit prior to the gasification evaluations. The gasification evaluations were performed using a thermal analysis system (TG/DTG) operated at temperatures of up to 1000 °C. The reactivity, [...]

1169 6330

Open Access Original Research

Effect of Microwave Radiation on the Development of a Porous Aluminum Carrier of the Active Mass of Catalysts in Heterogeneous Catalytic Reactions

Received: 24 June 2022;  Published: 26 September 2022;  doi: 10.21926/cr.2203030

Abstract

In this study, we prepared a fine-grained, aluminum-reinforced alumina support matrix of the active mass of catalysts, which showed activity in heterogeneous catalytic reactions stimulated by electromagnetic radiation in the microwave range. The support absorbed microwave radiation of 2.45 GHz. We compared the textural characteristics of samples of Al/Al2O3 supports obtained by conventional heat treatment to those synthesized by heat treatment in a microwave field. We found several advantages of heat treating poten [...]

1599 7309

Open Access Review

Microbial Cyclodextrin Glycosyltransferases: Sources, Production, and Application in Cyclodextrin Synthesis

Received: 11 June 2022;  Published: 22 September 2022;  doi: 10.21926/cr.2203029

Abstract

Cyclodextrin glycosyltransferase (CGTase) is a multifunctional enzyme that hydrolyzes the α-glycosidic bond between two sugar molecules and synthesizes cyclodextrins (CDs) and other transglycosylation products. It is a ubiquitously present extracellular enzyme that offers the CGTase-producing organism the sole right onto starch substrates over other microbes. The present review provides a brief account of diversity among CGTase-producing microbes, CGTase production in different heterologous hosts (wherein ext [...]

3710 25441

Open Access Original Research

Heterologous Expression, Characterization, and Comparison of Laccases from the White Rot Causing Basidiomycete Cerrena Unicolor

Received: 26 July 2022;  Published: 20 September 2022;  doi: 10.21926/cr.2203028

Abstract

Lignin is the most abundant renewable source of aromatics on earth, and conversion of it to chemicals and fuels is needed to build an economically viable renewable biofuels industry. Biological routes to converting lignin to fuels and chemicals involve depolymerizing lignin using lignin-degrading enzymes that catalyze the breaking of ether and carbon-carbon bonds in the phenolic and non-phenolic subunits of lignin. Laccases are a crucial class of lignin-degrading enzymes and are copper-containing enzymes capable of [...]

1547 9060

Open Access Research Article

Effective Cu/ZnO/Al2O3 Catalyst for Methanol Production: Synthesis, Activation, Catalytic Performance, and Regeneration

Received: 09 September 2021;  Published: 19 September 2022;  doi: 10.21926/cr.2203027

Abstract

A precursor CuO/ZnO/Al2O3 catalyst for methanol synthesis has been prepared at room temperature by introducing a ternary salt solution into the excess of sodium carbonate solution following the reverse co-precipitation method. The catalyst was tested for the synthesis of methanol from synthesis gas. The composition (vol. %) has been presented: CO, 22; CO2, 5.8; N2, 5.5; H2, balance. The methanol productivity was recorded to be 2.7 kg kgcat–1 h–1 at a temperature of 260 °С, a pressure of 3 MPa, and a [...]

4770 38708

Open Access Review

Design of Heterogeneous Catalysts for the Conversion of Furfural to C5 Derivatives: A Brief Review

Received: 30 June 2022;  Published: 13 September 2022;  doi: 10.21926/cr.2203026

Abstract

Technological development made in the field of biomass application allows synthesizing several high-value products, such as furfuraldehyde. Furfural, produced through sequential hydrolysis and dehydration reactions from biomass, is considered a platform molecule and a precursor of several other chemicals and biofuels that are generated following reactions such as hydrogenation, hydrodeoxygenation, and decarboxylation. This review aims to reveal the environmental-friendly mechanisms followed for producing furfural d [...]

2191 14313

Open Access Original Research

Removal of As(III) from Water by Cellulase Templated TiO2: A Photocatalytic Oxidation Conjugated Adsorption Process

Received: 16 July 2022;  Published: 09 September 2022;  doi: 10.21926/cr.2203025

Abstract

TiO2 photocatalyst was prepared using cellulase as a biotemplate through a hydrothermal process. The as-prepared catalyst was characterized based on physicochemical techniques and was used to remove As(III) from contaminated water. The cellulase templated TiO2 photocatalyst (TiO2-cellulase) had a large specific surface area, which reached 166.6 m2·g–1. It also had a strong oxidation ability and, thus, behaved well in both photocatalytic oxidation of As(III) and dark adsorption. The pH of the solution h [...]

1172 7051

Open Access Original Research

Biochemical Characteristics and Healing Activity of Bromelia laciniosa Leaf Protease

Received: 27 May 2022;  Published: 25 August 2022;  doi: 10.21926/cr.2203024

Abstract

Macambira plant (Bromelia laciniosa Mart. Ex Shult. & Schult. f.) is a species belonging to the family Bromeliaceae, which is distributed widely in the hinterlands of northeastern Brazil, from Bahia to Piauí states. The plants of this species contain an enzyme complex named bromelain, which has great potential for therapeutic applications. In the present study, bromelain derived from Bromelia laciniosa leaves was assessed for its thermodynamic properties and in vitro cytotoxic and healing activities. Bro [...]

1536 12183

Open Access Original Research

Fischer-Tropsch Synthesis on Co/SBA-15 Catalyst: Characterization and Oligomerization Modeling

Received: 05 May 2022;  Published: 16 August 2022;  doi: 10.21926/cr.2203023

Abstract

In this study, we investigated the oligomerization mechanism of the Fischer-Tropsch synthesis catalyzed by a cobalt-based catalyst supported by SBA-15. The Co/SBA-15 catalyst contained 20% w/w of cobalt. It was prepared by the wet impregnation method and characterized by X-ray diffraction (XRD), N2 adsorption-desorption, temperature-programmed reduction (TPR), and scanning electron microscopy coupled to X-ray energy dispersion spectroscopy (SEM-EDS). The FT synthesis was conducted in a slurry bed reactor operating [...]

1753 8992

Open Access Original Research

Degradation of Amido Black Dye Using Ultra-Violet Light Catalyzed by Iron Oxide Nanoparticles: Kinetics and Mechanism of Degradation

Received: 26 June 2022;  Published: 25 July 2022;  doi: 10.21926/cr.2203022

Abstract

In this study, we investigated the degradation of amido black dye in an aqueous solution using ultra-violet (UV) light catalyzed by iron oxide nanoparticles (nano-Fe). The nano-Fe was synthesized by sodium borohydride reduction of ferric chloride solution and was characterized by scanning electron microscopy (SEM), X-ray diffraction (XRD), and X-ray fluorescence spectrophotometry (XRF). The SEM of the nano-Fe showed regular spherical particles, the XRD examination showed a weak and broad peak at Fe (1 1 0), and the [...]

1490 8846

Open Access Original Research

Hydrocracking of Di-and Triaromatic Hydrocarbons to Monoaromatics over Mixed Bi-functional Catalysts

Received: 10 January 2022;  Published: 19 July 2022;  doi: 10.21926/cr.2203021

Abstract

In this study, we present selective hydrocracking of poly (di and tri) aromatic compounds to monoaromatics, such as benzene, toluene, and xylenes (BTX), over a mixture of Pt/Al2O3 and Y zeolites. The polyaromatic compounds feed is a combined simulated model feed, which is similar to light cycle oil (LCO) in composition. The feed is processed in a fixed bed reactor over a catalyst mixture: in the first step, selective hydrogenation of di and tri-aromatic compounds occurs in the presence of Pt/Al2O3 catalyst, followe [...]

2211 12179

Open Access Original Research

Homogeneous {Ti2Ni} Heterotrinuclear Catalyst for Ethylene Polymerization and Copolymerization

Received: 18 May 2022;  Published: 06 July 2022;  doi: 10.21926/cr.2203020

Abstract

We synthesized and spectroscopically characterized a new heterotrimetallic {Ti2Ni} ethylene (co)polymerization precatalyst containing one (α-diimine)NiBr2 and two (phenoxy-imine)TiCl4 scaffolds. Its calculated structure was investigated at the DFT B3LYP/LACVP** level. Our calculations showed that the titanium(IV) centers were in a slightly distorted trigonal bipyramidal environment, and the average Ti···Ni distance was 8.76 Å. The precatalyst was used for synthesizing polyethylene a [...]

1507 10896

Open Access Review

Zeolite-Containing Catalysts in Alkylation Processes

Received: 05 May 2022;  Published: 05 July 2022;  doi: 10.21926/cr.2203019

Abstract

This article provides an overview of zeolite-containing catalysts used in the alkylation of benzene and toluene with olefins, isobutane with butenes and butane-butene fractions, gasoline and oil fractions with olefins, propane-propylene, and butane-butylene fractions of catalytic cracking. Zeolites have various types of structures, including BEA, MFI, MWW, FAU, etc., which differ in pore size and the number and location of the channels. High-silica zeolites have a large pore volume, high acidity, good hydrothermal [...]

4656 23871

Open Access Research Article

Co2+ Doping and Molecular Adsorption Behavior of Anatase TiO2 (001) Crystal Plane

Received: 10 May 2022;  Published: 04 July 2022;  doi: 10.21926/cr.2203018

Abstract

TiO2 (001) crystal plane exhibits molecular adsorption and photocatalytic activity. The loading capacity of reactive oxygen species present on crystal planes helps in the significant improvement of catalytic activity. The methods of synthesis and conditions of existence significantly affect the molecular adsorption properties of crystal planes, which in turn affects the ability of the system to load reactive oxygen species. Herein, we report the simulation of the molecular adsorption behavior on the TiO2 (001) usin [...]

1410 9337

Open Access Original Research

Dearomatization of the Kerosene Fraction: Kinetic Studies

Received: 09 January 2022;  Published: 28 June 2022;  doi: 10.21926/cr.2202017

Abstract

The kinetics of dearomatization of a kerosene fraction processed using a zeolite catalyst (0.9 HZSM-5) at different temperatures (160-200°C), the molar ratio between the aromatic hydrocarbons present in the kerosene fraction and n-decene (1:(0.5-4)), and the reaction time (1-3 h) were studied. Based on the obtained data, a kinetic model for kerosene dearomatization is proposed. It is assumed that the single-center Riedel mechanism is followed. The stage associated with the interaction between n-decene adsorbed on t [...]

1560 9022

Open Access Research Article

3D Fe3O4-decorated Nitrogen-doped Graphene Aerogel as a Highly Durable Electrocatalyst for Oxygen Reduction Reactions

Received: 29 April 2022;  Published: 21 June 2022;  doi: 10.21926/cr.2202016

Abstract

The rational design of efficient electrocatalysts for oxygen reduction reaction (ORR) is the key to developing fuel cells and metal-air batteries. Carbon-supported iron-based materials, as the most promising electrocatalysts for ORR, have drawn much attention as they are cost-effective and exhibit high activity. In this work, a three-dimensional (3D) Fe3O4-decorated N-doped graphene aerogel (Fe3O4/NGA) catalyst was synthesized following a simple hydrothermal method which was followed by an annealing process. The co [...]

1798 10520

Open Access Original Research

Synthesis of a Solid Base Catalyst Formed from Zinc(II) Acetylacetonate and Consisting of MgO Modified with ZnO

Received: 28 April 2022;  Published: 06 June 2022;  doi: 10.21926/cr.2202015

Abstract

Solid base catalysts consisting of MgO modified with 10 mol% ZnO (ZnO/MgO) were prepared by depositing zinc(II) acetylacetonate (Zn(acac)2) in polar and nonpolar organic solvents on the surface of MgO and Mg(OH)2. The process was followed by thermal decomposition in air at 773 K over a period of 3 h. The activity of MgO modified with Zn(acac)2 for base-catalyzed retroaldol reaction (the decomposition of diacetone alcohol (4-hydroxy-4-methyl-2-pentanone) to acetone) at 299 K was higher than the activity of unmodifie [...]

1310 9606

Open Access Original Research

Visible-Light-Induced Formation of Aromatic Ketones: A Metal-Free C−H Oxygenation Process in Air under Room Temperature

Received: 01 April 2022;  Published: 10 May 2022;  doi: 10.21926/cr.2202014

Abstract

The process of light-induced C-H oxygenation is of high interest as it can be used for the construction of oxygenated compounds. Herein, we report a mild and general method for the efficient synthesis of aromatic ketones following the process of metal-free C-H oxygenation. With air as the oxidant, high functional tolerance was demonstrated, and the desired ketones were obtained in moderate to excellent yields at room temperature (25 oC). Mechanistic studies suggested that the oxidative transformation potentially oc [...]

1540 10567

Open Access Review

Lipases: Sources of Acquisition, Ways of Production, and Recent Applications

Received: 16 February 2022;  Published: 07 May 2022;  doi: 10.21926/cr.2202013

Abstract

Enzymes are extensively used in biotechnological processes in several areas of industry. They are sustainable and safe, and their specificity is another characteristic that improves the performance in the process. Among enzymes, lipase is relevant due to the ability to play different roles in the industry and the possibility of collecting them from microbial sources that are found in industrial residues. This can reduce the costs of enzyme production. In relation to that, lipase immobilization is an interesting pro [...]

3234 39421

Open Access Review

Recent Advances in the Application of Perovskite Catalysts in the Dry Reforming of Methane

Received: 29 January 2022;  Published: 26 April 2022;  doi: 10.21926/cr.2202012

Abstract

The use of the dry reforming of methane (DRM) to convert the two principal greenhouse gases, methane and carbon dioxide, to syngas (a mixture of H2 and CO) has attracted increasing attention in recent years. However, the DRM reaction suffers from the twin disadvantages of carbon deposition and sintering, so a highly efficient and robust catalyst with superior anti-deactivation properties is required. One way to meet this need is to incorporate active metals into crystalline oxides, such as perovskite. In this paper [...]

1856 13997

Open Access Original Research

Pd-Cu Bimetallic Based Catalysts for Nitrate Remediation in Water: Synthesis, Characterization, and the Influence of Supports

Received: 29 January 2022;  Published: 21 April 2022;  doi: 10.21926/cr.2202011

Abstract

The use of Pd-Cu bimetallic catalysts in the reduction of aqueous nitrate ions by hydrogen was studied. The catalysts were supported on multi-walled carbon nanotubes (MWCNTs), activated carbon (AC), and Titania, and the influence of the support on the nitrate reduction activity in water was then investigated. The catalysts were characterized before and after use by FT-IR, XRD, SEM, EDX, and Laser Granulometry. It was found that the surface characteristics of the support have an influence on the catalyst activity, w [...]

1743 12393

Open Access Communication

A New Chiral Cyclopalladated Ferrocenylimine Self-assembly Polymeric Film supported on Silicon for Heck and Suzuki-coupling Reactions

Received: 21 March 2022;  Published: 14 April 2022;  doi: 10.21926/cr.2202010

Abstract

A new chiral cyclopalladated ferrocenyl imine catalyst (called 4a2) was designed and synthesized, and its self-assembly catalytic polymeric brush supported on silicon (denoted as Si@PB4a2) was also fabricated by surface-initiated atom transfer radical polymerization (ATRP) and characterized. The catalytic properties of monomer 4a2 in homogeneous and Si@PB4a2 in heterogeneous in Heck and Suzuki cross-coupling were investigated, respectively. They exhibited higher catalytic activity in Heck, and Suzuki coupling react [...]

1723 9103

Open Access Original Research

Hierarchical MFI Zeolite Catalysts: How to Determine Their Textural Properties?-A Comparative Study

Received: 26 January 2022;  Published: 14 April 2022;  doi: 10.21926/cr.2202009

Abstract

It is important to elucidate the role of the surface areas and pore volumes of hierarchical zeolites to understand their behavior as catalysts. Micro-and mesopore surface areas and volumes of the hierarchical MFI (Mobil Five zeolites) were assessed following several methods: (i) N2 adsorption at 77 K using classical and corrected t-plot analyses methods, (ii) pre-adsorption of n-nonane was followed by the study of the N2 adsorption at 77 K, and (iii) non-local-density functional theory (NLDFT) analysis using either [...]

2676 21917

Open Access Original Research

Preparation of a Novel Bi2MoO6/Ag/Ag2CrO4 Catalyst with Promoted Visible Light Photodegradation of RhB Dye

Received: 29 January 2022;  Published: 07 April 2022;  doi: 10.21926/cr.2202008

Abstract

A series of novel Bi2MoO6/Ag/Ag2CrO4 heterostructure photocatalysts (denoted as BA-X, X = 1, 3, 5, 10) were synthesized using a coprecipitation method. These photocatalysts were characterized by scanning electron microscopy (SEM), X-ray diffraction (XRD), UV-vis spectroscopy, and X-ray photoelectron spectroscopy (XPS) and their photocatalytic properties were investigated. Compared with pure Bi2MoO6 or Ag2CrO4, BA-5 exhibited a higher photocatalytic property and broader light absorption. In addition, the surface pla [...]

1711 11545

Open Access Research Article

The Use of Composite TiO2/Activated Carbon Fibers as a Photocatalyst in a Sequential Adsorption/Photocatalysis Process for the Elimination of Ciprofloxacin

Received: 20 January 2022;  Published: 15 March 2022;  doi: 10.21926/cr.2201007

Abstract

This work reports the performance of a sequential adsorption/photocatalysis process using activated carbon fibers with deposited TiO2 for the elimination of the antibiotic ciprofloxacin (CIP) in water. A commercial activated carbon fiber (ACF10) was selected as the support, and a TiO2 coating was synthesized using Metal Organic Chemical Vapor Deposition (MOCVD). Experiments were carried out using a photocatalytic reactor irradiated with monochromatic LEDs (365nm). Two different processes have been studied: adsorpti [...]

1585 11138

Open Access Review

Recent Progress in the Development of Molecular Electrocatalysts for Formate Oxidation

Received: 31 December 2021;  Published: 22 February 2022;  doi: 10.21926/cr.2201006

Abstract

Fuel cells based on renewable synthetic fuels are promising alternatives to fossil fuel combustion for efficient electricity production. Much focus has been placed on hydrogen as a chemical fuel, but being a flammable gas, there are challenges with its safe handling. Formic acid is an attractive liquid fuel for use in direct formic acid or formate fuel cells, and it can in principle be produced from the thermal or electrochemical reduction of carbon dioxide. Over the past ten years, advances have been made in the d [...]

1727 12122

Open Access Original Research

Determining the Band Alignment at the BiVO4|NiOOH Interface Using the Hybrid DFT Technique

Received: 29 November 2021;  Published: 21 February 2022;  doi: 10.21926/cr.2201005

Abstract

It is important to understand the band offsets between semiconductors, which are crucial to determine the direction of electron transfer at the interfaces. Two methods are normally used to determine the direction from the first principles: alternating slabs put in contact (without empty spaces between them) and separate calculations for each material surface in the presence of vacuum spaces. The first method may introduce distortions due to insufficient epitaxial match, which may lead to bandgap changes, and the se [...]

1532 9711

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