Fabrication and Catalytic Property of an Ordered Terpyridine Pd(II)/Ni(II) Catalytic Monolayer for Suzuki Coupling Reactions
Abstract
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Fabrication and Catalytic Property of an Ordered Terpyridine Pd(II)/Ni(II) Catalytic Monolayer for Suzuki Coupling ReactionsAbstract
Fabrication, arrangement, and controllable composition of ordered organometallic films are critical for designing a highly active catalyst and investigating the catalytic mechanism. In this paper, an organometallic terpyridine Pd(II)/Ni(II) monolayer linked on the silicon substrate surface (denoted as Si-Tpy-Pd1/Ni1) was prepared and characterized using water contact angle, ultraviolet spectra, X-ray diffraction, scanning electron microscopy, and X-ray photoelectron microscopy. Si-Tpy-Pd1/Ni1 exhibited high catalyt [...] 1118 7831 |
Hydrochemical Characteristics of Groundwater in the Mutoshi Deposit Environment, Kolwezi (Lualaba, DR Congo)Abstract
This study examines the hydrochemical characteristics of groundwater in the Mutoshi mining environment in Kolwezi, Democratic Republic of Congo, addressing gaps in understanding the impact of mining on water quality. Despite the DRC's vast water resources, only 26% of the urban population has access to safe drinking water, with the Mutoshi aquifer, providing over a quarter of Kolwezi's drinking water, facing deterioration due to underlying copper and cobalt-rich geological formations. Groundwater and geological sam [...] 1168 7830 |
Research and Application of Modified ZSM-5 for the Process of Alkylation of Oil Distillate FractionsAbstract
In the oil distillate fraction alkylation process, a modified Zr zeolite ZSM-5 was obtained and studied. The modification was executed using a method that impregnated ZSM-5 with a 5% solution of ZrOCl2∙6H2O. X-ray diffraction studies were conducted on zeolite ZSM-5, zirconyl chloride modifier ZrOCl2∙6H2O, and modified zeolite ZSM-5-ZrO2, which was calcined at temperatures of 200, 400, and 550°C. The results revealed that the phase composition of modified ZSM-5-ZrO2 zeolite samples varied depending on the calcinatio [...] 1205 7826 |
Saving is Losing: Pumping Cost vs. GHG Emissions in Water Distribution SystemsAbstract
Global climate change has necessitated the reduction of GHG emissions. Water distribution system (WDS) pumping adds to these emissions and, therefore, should be reduced. Under electricity hourly cost tariffs, utilities are incentivized to pump during the nighttime hours. This can have a deleterious effect, however, on GHG emissions. To quantify this effect, a modeling study of twelve real WDSs was performed with an electricity tariff. The systems all had the typical tank-level-based pump controls but also time-base [...] 1567 7826 |
Prolonged and Resistant Cutaneous Infection in Newly Transplanted Renal Patientby
Abstract
Mucormycosis is an angioinvasive and potentially fatal fungal infection caused by ubiquitous filamentous fungi. Cutaneous mucormycosis is an emerging infection and potentially lethal. Our aim was to review the literature on cutaneous mucormycosis. We present a case of a renal transplant patient with a surgical wound infection 20 days after kidney transplant. This case is an example on how early diagnosis is crucial and, since culture is less sensitive, microscopic evaluation of the characteristic broad hyphae is th [...] 1260 7821 |
Coronavirus Disease 2019 (COVID-19) Pandemic’s Effect on Child and Adolescent Mental Health: Analysis of Pediatric Intensive Care Unit and Consultation-Liaison Psychiatry Serviceby
Abstract
The Coronavirus Disease (COVID-19) pandemic has contributed to a co-occurring psychiatric epidemic. Children and adolescents have been particularly impacted, with disruptions in continuity of learning and healthcare. Psychological stressors such as fear of infection, boredom, decreased socialization, supply shortages, and incomplete information have contributed to low mood, irritability, insomnia, and emotional exhaustion. Our study contributes to this research by quantifying the devastating psychiatric toll that t [...] 1140 7820 |
Nanomaterials with Plant or Animal Origin for Greener Biodelivery and Biosensor Applications: A ReviewAbstract
Nanomaterials are now used in almost every field of science; as conductors and electrodes in electronics, as nanodelivery systems in health screenings and drug delivery, as nanofibrils in filtering and textile industry, as nanoparticles in biosensor fabrication for toxin and pathogen detection, and in packaging materials in the food industry. Synthetic materials and plastics accumulate in the environment causing increasing health concerns for their use in food and pharmaceutical products. Therefore, researchers now [...] 1476 7818 |
Human Interference with the Earth Has Abolished the Next Ice Age but Overdosing with Carbon Dioxide Emissions Could Have Catastrophic ConsequencesAbstract
Around 1600 AD the carbon dioxide content of the earth’s atmosphere started to rise, even whilst according to the Milankovitch [1] astronomical theory of climate variation it was due to fall. On the natural earth the carbon dioxide count of the atmosphere is a delayed response and an enhancing feedback on the basic cause of the Milankovitch astronomical cycle, the intensity of the June sunshine. If the Milankovitch cycle had continued its natural course, the medevial cold period known as the little ice age. Human i [...] 1163 7809 |
Evaluation of a Virtual Compassionate Living Group for Patients with Chronic PainAbstract
Chronic pain affects around 28 million people in the UK. Those living with chronic pain can frequently experience internalised self-stigma and negative self-evaluations as a result of the pain itself and due to difficult life experiences. Previous research has found Compassion Focused Therapy to be effective for people living with long term health conditions like chronic pain. The current study sought to evaluate a routine Virtual Compassionate Living Group for patients with chronic pain on the measures of self-com [...] 1308 7802 |
Mitochondria, Brain, Heart and Bodyby
Abstract
More and more studies revealed links amongst neurological disorders, heart diseases and cancers. For example, people with subclinical cardiovascular diseases are at higher risk for Alzheimer's disease, Parkinson’s disease is associated with varied risk of cancer, Autism Spectrum Disorders and cancer have overlapping genes and molecular pathways, heart disease and cancer share common risk factors, etc. It is intriguing how are these conditions that appear to be completely different linked together. 1483 7802 |
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