Open Access Original Research

Homogeneous {Ti2Ni} Heterotrinuclear Catalyst for Ethylene Polymerization and Copolymerization

Received: 18 May 2022;  Published: 06 July 2022;  doi: 10.21926/cr.2203020

Abstract

We synthesized and spectroscopically characterized a new heterotrimetallic {Ti2Ni} ethylene (co)polymerization precatalyst containing one (α-diimine)NiBr2 and two (phenoxy-imine)TiCl4 scaffolds. Its calculated structure was investigated at the DFT B3LYP/LACVP** level. Our [...]