Versatility of Supported Gold Nanoparticles on Hydrotalcites used for Oxidation and Reduction Reactions
Abstract
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Versatility of Supported Gold Nanoparticles on Hydrotalcites used for Oxidation and Reduction Reactionsby
Abstract
Regardless of their size, supported gold nanoparticles are largely used for liquid-phase oxidation reactions. Small gold nanoparticles exhibit good performance during the reduction of organic compounds. The direct reduction of carboxylic acid to aldehyde is a famous and familiar reaction in the field of organic chemistry and is considered as one of the fundamental chemical transformations. Herein, we present Au/hydrotalcite, Au/MgO, and Au/Al2O3 systems as heterogeneous versatile catalysts to realize the oxidation [...] 2111 12326 |
Effect of Acid Treatment on the Properties of Zeolite Catalyst for Straight-Run Gasoline UpgradingAbstract
The objective of this research was to analyze the effect of different concentrations of nitric and hydrochloric acids on the structural, acidic, and catalytic properties of a post-synthetic treated ZSM-5 type zeolite at various temperatures. The properties of zeolite catalysts were determined using different methods, such as the Brunauer-Emmett-Teller (BET) method for specific surface area, temperature-programmed desorption (TPD) of ammonia method for acidic properties, and a flow-through unit with fixed bed cataly [...] 3993 19871 |
Stability of a Fe-Rich Cathode Catalyst in an Anion Exchange Membrane Fuel Cellby
Abstract
Fe-rich alloys have been widely studied as catalyst materials for the cathodic oxygen reduction reaction (ORR) in hydrogen fuel cells, and many have shown high activities. The stability of Fe-rich catalysts has also been researched, and some studies have shown promising results using an accelerated stress test (AST), which uses a potential cycling method. However, for commercial fuel cell applications, such as standby power systems, the catalyst has to tolerate a high potential for a long period, which can not be r [...] 1762 11707 |
Photocatalytic Degradation of Azo Dyes Using Microreactors: Mechanistic Study of its Effects on H2O2 AdditionAbstract
The photocatalytic reaction involved in TiO2 photocatalysis was investigated using a microreactor coated with TiO2 film on the glass plate attached on one side of the microreactor. It was confirmed that the effect of H2O2 on the photocatalytic degradation efficiency of azo dyes (acid orange 7, acid red 151, and acid yellow 23) was dependent on the polymorphs (anatase and rutile) of TiO2 coated on the glass plate of the UV-irradiated microreactor. Scavengers of holes (KI) and electrons (p-benzoquinone) were added to [...] 2382 13526 |
Development of an Efficient Bi-Functional Catalyst made of a Novel Hybrid Material for Rechargeable Zn-Air BatteryAbstract
One-pot synthesis of mesoporous hybrid material consisting of Mn-Co/CoO nanoparticles encapsulated in an N-doped graphene shell decorated with Mo2C nanoparticles (Mo2C-NC@Mn-Co/CoO) was reported. The Mn and Mo components synergistically refined the graphitized carbons due to the interactions with N and C atoms while promoting the stability of the Co/CoO nanoparticles. These components exhibited a beneficial effect on the dispersion of the active metal/metal oxide nanoparticles and the formation of a mesoporous stru [...] 4875 18007 |
A Systems Guide to Sustainable Construction Across the Project Life Cycle: A Technical Review from Impacts to Interventionsby
Abstract
Sustainable construction practices and robust waste management strategies provide a viable pathway to mitigate these challenges. By integrating resource-efficient design, circular economy principles, and environmentally responsible technologies, the industry can significantly reduce its ecological burden. This paper presents a synthesis of environmental impacts from construction and a practical playbook of interventions spanning design, delivery, operations, and end-of-life. The study is organized as a systems guid [...] 38 139 |
Dynamic Removal of Hexavalent Chromium from Aqueous Solution and Realwastewater Using Raw Cordia africana Sawdust in a Fixed-Bed Column SystemAbstract
This study evaluated the dynamic performance of raw Cordia africana sawdust for hexavalent chromium (Cr(VI)) removal in a fixed-bed column system under varying operating conditions, using both synthetic solutions and real tannery wastewater. This represents the first comprehensive investigation combining fixed-bed operation, real wastewater validation, triple-model comparison, speciation analysis, and regeneration assessment for this locally abundant Ethiopian biomass. Fixed-bed column experiments were conducted at [...] 63 216 |
Causal Relationship Between Climate Pressures and Agricultural Producer Prices in Türkiye; the Toda Yamamoto ApproachAbstract
Increases in greenhouse gas emissions, a key indicator of climate change, pose significant risks and uncertainties for the agricultural industry. From a theoretical supply-side perspective, greenhouse gas emissions may be associated with agricultural productivity losses and, consequently, with potential upward risks for producer prices. However, the Toda-Yamamoto framework used in this study tests predictive Granger causality rather than the magnitude or sign of a structural price effect. This study examines the pr [...] 80 217 |
Physicochemical and Lignocellulosic Characterization of Jackfruit (Artocarpus heterophyllus) Processing Waste as a Potential Biomass ResourceAbstract
A Considerable amount of peel, rind, core, and fibrous residues are produced from the processing of Jackfruit (Artocarpus heterophyllus Lam.), which are generally discarded, though they contain valuable lignocellulosic components. Limited information is available on the composition of the combined jackfruit processing waste stream. Thus, the present study evaluates the physicochemical and lignocellulosic properties of jackfruit processing waste obtained from local markets and prepared with equal proportions of peel [...] 118 377 |
Seasonal Urban Heat Persistence and Nighttime Radiance Intensification in Jaipur, India: Spatiotemporal AnalysisAbstract
Urban thermal environments reflect the relationship between land surface temperature (LST) and anthropogenic activity. The present study analyses seasonal land surface temperature, the Urban Thermal Field Variance Index (UTFVI), and night-time radiance in Jaipur, India from 2014 to 2025 using Landsat 8 Collection 2 and VIIRS Day/Night Band datasets. The Summer (April-June) and winter (November-December) median composites were generated for continuous analysis and for classified assessment. In the study, five LST an [...] 264 664 |
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