Effect of Acid Treatment on the Properties of Zeolite Catalyst for Straight-Run Gasoline Upgrading
Abstract
3505 18108
Effect of Acid Treatment on the Properties of Zeolite Catalyst for Straight-Run Gasoline UpgradingAbstract
The objective of this research was to analyze the effect of different concentrations of nitric and hydrochloric acids on the structural, acidic, and catalytic properties of a post-synthetic treated ZSM-5 type zeolite at various temperatures. The properties of zeolite catalysts were determined using different methods, such as the Brunauer-Emmett-Teller (BET) method for specific surface area, temperature-programmed desorption (TPD) of ammonia method for acidic properties, and a flow-through unit with fixed bed cataly [...] 3505 18108 |
Stability of a Fe-Rich Cathode Catalyst in an Anion Exchange Membrane Fuel Cellby
Abstract
Fe-rich alloys have been widely studied as catalyst materials for the cathodic oxygen reduction reaction (ORR) in hydrogen fuel cells, and many have shown high activities. The stability of Fe-rich catalysts has also been researched, and some studies have shown promising results using an accelerated stress test (AST), which uses a potential cycling method. However, for commercial fuel cell applications, such as standby power systems, the catalyst has to tolerate a high potential for a long period, which can not be r [...] 1539 11108 |
Photocatalytic Degradation of Azo Dyes Using Microreactors: Mechanistic Study of its Effects on H2O2 AdditionAbstract
The photocatalytic reaction involved in TiO2 photocatalysis was investigated using a microreactor coated with TiO2 film on the glass plate attached on one side of the microreactor. It was confirmed that the effect of H2O2 on the photocatalytic degradation efficiency of azo dyes (acid orange 7, acid red 151, and acid yellow 23) was dependent on the polymorphs (anatase and rutile) of TiO2 coated on the glass plate of the UV-irradiated microreactor. Scavengers of holes (KI) and electrons (p-benzoquinone) were added to [...] 2149 12930 |
Development of an Efficient Bi-Functional Catalyst made of a Novel Hybrid Material for Rechargeable Zn-Air BatteryAbstract
One-pot synthesis of mesoporous hybrid material consisting of Mn-Co/CoO nanoparticles encapsulated in an N-doped graphene shell decorated with Mo2C nanoparticles (Mo2C-NC@Mn-Co/CoO) was reported. The Mn and Mo components synergistically refined the graphitized carbons due to the interactions with N and C atoms while promoting the stability of the Co/CoO nanoparticles. These components exhibited a beneficial effect on the dispersion of the active metal/metal oxide nanoparticles and the formation of a mesoporous stru [...] 4528 16997 |
DWSIM-Based Process Simulation and Exergy Analysis of Bioethanol Production from Rice Huskby
Abstract
The growing concerns over fossil fuel dependency have motivated the exploration of sustainable biofuel alternatives. However, the practice of utilizing first-generation bioethanol production obtained majorly from food crops threat food supply market and poses threat to food security and land use. As a way forward, second-generation bioethanol from biomass, such as rice husk, an abundant agricultural residue, could potentially offer a promising pathway. Yet, its conversion remains energy-intensive and thermodynamica [...] 234 624 |
Cr(VI) Adsorptive Removal Using Raw Cordia africana Sawdust: Optimization of Operating Parameters, Kinetics, Isotherm, Thermodynamics, and Desorption EfficiencyAbstract
Hexavalent chromium (Cr(VI)) is a carcinogenic pollutant commonly found in wastewater from tanning and electroplating industries. This study investigates the efficiency of raw Cordia africana sawdust as a biosorbent for Cr(VI) removal. Batch adsorption experiments were conducted by varying pH (3-8), contact time (10-120 min), and Cr(VI) concentration (21-47 mg/L) using Response Surface Methodology (RSM) with Box-Behnken design. Characterization was performed using FTIR, SEM, BET, pH, and PZC analysis before and aft [...] 184 568 |
Sustainable and Environmentally Friendly Approaches for Eliminating Alizarin Red S from Contaminated Water Using Hydroxyfluorapatite-Based BiomaterialsAbstract
This study investigated the use of new bioadsorbent the Hydroxyfluorapatite (Ca10(PO4)6OH1.75F0.25, HFA) to eliminate Alizarin Red S (ARS), a harmful water pollutant. Initial batch tests were conducted to evaluate the adsorption process, focusing on both kinetics and equilibrium behavior. Various kinetic models were applied such as: pseudo first-order, pseudo second order, the intraparticular diffuision model and external diffusion model. The modeling results proved that the pseudo-second-order model best matched t [...] 292 884 |
Restoring the Resilience of Water-Energy-Food Nexus Based on Desalination through Biomass Management: Case Study West Mani, Greeceby
Abstract
Mediterranean regions like West Mani, Greece, face escalating water scarcity exacerbated by climate variability and seasonal tourism peaks, straining the water-energy-food (WEF) nexus. Olive cultivation, central to the region’s economy and culture, generates substantial underutilized biomass residues that increase wildfire risk if left unmanaged. At the same time, water supply increasingly relies on energy-intensive desalination and pumping. This study addresses the gap in integrated, place-based WEF nexus applicat [...] 660 2283 |
Hydroclimatic Variability and Precipitation Extremes in Sindh under a Changing ClimateAbstract
Sindh Province, Pakistan, is highly vulnerable to hydroclimatic extremes, necessitating a detailed understanding of its precipitation patterns for effective water management. This study assesses spatiotemporal precipitation dynamics across Sindh from 2001 to 2024 by integrating satellite-based CHIRPS data, in situ observations from the Climate Knowledge Portal (CKP), and CMIP6 climate model projections. Validation results show strong agreement between CHIRPS and ground data (R ≈ 0.87, d ≈ 0.93), confirming the sate [...] 624 1961 |
Characterization of Drought Severity Using GRACE and TerraClimate Dataset in the Rift Valley Basin, EthiopiaAbstract
Characterizing drought severity using GRACE and TerraClimate datasets is globally important because it enables consistent, large-scale monitoring of both surface and subsurface water availability across data-scarce regions. This integrated perspective supports improved drought assessment, climate change impact analysis, and informed water-resource management worldwide. The Ethiopian Rift Valley has experienced recurrent hydrological drought hazards, posing serious threats to water availability, agricultural product [...] 670 2034 |
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