Lithium-ion Battery and the Future
The Graduate Center, The City University of New York, 365 Fifth Avenue, New York, NY, 10016, USA
Department of Engineering, Physics, and Technology, Bronx Community College, The City University of New York, 2155 University Avenue, Bronx, NY 10453, USA
Department of Applied Physics, New York University, 6 Metro-tech Center, Brooklyn, New York 11201, USA
Academic Editor: Hossein Hosseinkhani
Received: December 26, 2020 | Accepted: March 25, 2021 | Published: April 14, 2021
Recent Progress in Materials 2021, Volume 3, Issue 2, doi:10.21926/rpm.2102012
Recommended citation: Mananga ES. Lithium-ion Battery and the Future. Recent Progress in Materials 2021; 3(2): 012; doi:10.21926/rpm.2102012.
© 2021 by the authors. This is an open access article distributed under the conditions of the Creative Commons by Attribution License, which permits unrestricted use, distribution, and reproduction in any medium or format, provided the original work is correctly cited.
Light-matter interaction at the nanometer scale lies at the heart of many physical problems including spectroscopic techniques to characterize lithium-ion batteries (LIBs). One of the most important topics in time-dependent quantum mechanics for physicists and chemists is the description of spectroscopy, which refers to the study of matter through its interaction with light fields. Classically, light-matter interactions are a result of an oscillating electromagnetic field resonantly interacting with charged particles. Quantum mechanically, light fields will act to couple quantum states of the matter. Light-matter interactions are fundamentally quantum electrodynamical. In many cases, they are described as quantum transitions by electrons, accompanied by the emission, absorption or scattering of quanta of photons . Over the past few decades, several experiments have investigated electromagnetic waves’ interaction with various materials used in LIBs for the benefit of society [2,3,4]. Currently, research in the battery community is still extensive due to novel techniques and their applications in LIBs and beyond . Usually, one technique is not sufficient to fully characterized LIB materials. One needs to combine more than one technique to characterize one single material [6,7,8,9]. When several techniques are used to characterize one type of material, these techniques are applied at different timescales and periods. This fact must be taken into consideration when analyzing data of different techniques obtained at different life span of the material [10,11,12,13,14].
Batteries are devices that transform chemical energy into electricity and consist of electrochemical cells that are electrically connected . Historically, the modern battery was developed by Alessandro Volta in 1800 . Shortly after Volta, Gaston Plante invented the lead-acid battery in 1859 . As time went by, Georges Leclanche introduced the zinc-carbon battery (Leclanche cell) in 1866, which is one of the first modern electric batteries and the precursor of the modern dry cell battery . In 1899, Ernst Jungner invented the nickel-cadmium battery (NiCd) . The effort on nickel metal hybrid (NiMH) batteries began at the Battelle-Geneva Research Center following the technology's invention in 1967. An interest grew in the 1970s with the commercialization of the nickel-hydrogen battery for satellite applications . Research carried out by the CNRS in France and the Philips Laboratories developed new high-energy hybrid alloys incorporating rare-earth metals for the negative electrode . However, these high-energy hybrid alloys suffered from alloy instability in alkaline electrolyte and consequently insufficient cycle life. The first consumer-grade NiMH cells became commercially available in 1989 . In 2008, more than two million hybrid cars worldwide were manufactured with NiMH batteries. The battery directive in the European Union makes NiMH batteries replace Ni–Cd batteries for portable consumer use . In advanced Ni-MH batteries, the positive electrode is nickel hydroxide (NiOOH) used with optimum amounts of additives (such as Co(OH)2, Y2O3, graphite powders, etc.) to enhance the electrical conductivity of the cathode for higher charge efficiency [24,25,26]. In the last few years, nickel hydroxide production technology and its utilization techniques in Ni-Cd and Ni-MH batteries have increased. Because of the importance of secondary batteries, significant investments have been made in this area in the last decade. A new perspective on the mass scale production could be timely to the battery community. Ni-MH batteries have been drawing increasing attention due to their high discharge rate with relatively less heat dissipation [27,28]. This technology has gained worldwide attention throughout the market for its ever-increasing demands for communication, space, and defense applications due to its unique features such as long-term life cycle at the profound depth of discharge.
Pioneering work of the lithium battery began in 1912 under Gilbert Lewis, but it was until early 1970s that the first non-rechargeable lithium batteries were commercially available to the general public [29,30]. Attempts to develop rechargeable lithium batteries in the 1980s failed due to safety problems . A breakthrough came out in 1985 when Akira Yoshino and his co-workers identified that certain qualities of petroleum coke were stable under the required electrochemical conditions . These effective anode materials allowed Yoshino to develop an efficient and working LIB based on the ion transfer cell configuration [33,34]. Thus, the graphite was thus used as an anode and LixCoO2 was also good enough to be a material used as a cathode . These discoveries and developments ultimately led to the release of a commercial lithium battery in 1991 by SONY. Today, this chemistry has become the most promising and fastest-growing battery on the battery research15. For the past 30 years, LIBs are the most popular rechargeable energy storage devices in consumer electronics. They are the leading contenders for powering commercially viable electric vehicles in the near future . Nearly, 70,000 major scientific journals on LIBs have been published from 1990 to 2020, but none of these articles (research/review articles) explore all the diagnostic studies of the different techniques used to investigate the LIBs and beyond. LIBs have enabled the electronics revolution and electric vehicles are beginning to take off. They are also enabling renewable energy such as wind and solar . LIBs store chemical energy, delivering it in electric power with high efficiently and no exhaust emissions . While LIBs are widely used in portable electronics, their implementation into larger-scale applications is hindered by the electrode materials’ performance and the electrolyte . Safety is also a significant concern in LIB technologies, and many high-profile examples of runaway reactions have the community searching for advanced materials with better stability [40,41]. For instance, cathode materials such as the layered oxides (LiMO2) and most commercially available electrolytes exhibit a non-negligible instability at the end of the charging process . To overcome these safety concerns, alternative material systems are under intense investigation to enhance safety and chemical stability over a wide range of ambient and operating temperatures . As recently reported by Whittingham , the success of LIB over the past 30 years comes with several responsibilities such as focusing on the need for a cleaner environment for both health and climate change mitigation; emphasizing the science rather than this will make the next greatest battery. A better understanding of the reaction mechanisms, thermodynamics and kinetics and a focus on fundamental science is important. Equally important, giving enough data allows direct comparison. The LIB development did not stop with the above seminal and important discoveries, but many improvements and alternatives have since been reported [45,46,47,48,49,50,51,52,53].
Recently, several electrode materials and electrolyte systems have been discovered, leading to improve the energy storage materials for the benefit of society . Table 1 names some electrode and electrolyte materials that have been used in the history .
Cathode materials, which account for about 45% of the cost of a whole battery, play an essential and decisive role in cell voltage and capacity. Disordered rock-salt (DRX) materials were shown to have facile Li transport enabled by a percolating network of Li-rich environments [54,55]. Their ability to function without requiring cation ordering has enabled novel cathodes with remarkable chemical diversity . In some cases, many new cathode materials, containing only earth-abundant elements (e.g., Fe, Mn, and Ti) have been developed in this category, such as Li1.3Mn0.4Nb0.3O2 , Li1.2Mn0.4Ti0.4O2 , Li1.2Ni1/3Ti1/3Mo2/15O2 , Li4Mn2O5 , and Li2FeV0.5Ti0.5O4  as well as their fluorinated variants [62,63,64,65,66].
The objective of this perspective article is to extend knowledge in the fields of materials chemistry such as the improvement of the capacity of LIBs in ways that will make green energy more accessible and commercially viable . Building a better LIB involves addressing several factors simultaneously. For instance, keeping the battery’s cathode electrically and ionically conductive to making sure that the battery stays safe after many cycles . A recent discovery published in the article Nature reports the development of a new cathode coating by using an oxidative chemical vapor deposition technique that can help solve several potential issues with LIBs all in one stroke . The polymer fabricated in this discovery called PEDOT consists of nickel-manganese-cobalt (NMC) cathode material, encapsulated with a sulfur-containing polymer . This polymer provides the cathode a layer of protection from the battery’s electrolyte as the battery charges and discharges. A recent article by Divakaran et al.  reviews a rational design on materials for developing next generation LIB. Divakaran et al. presents the historical and recent advancements in cathode and anode materials including the future scope of the lithium nickel manganese cobalt oxide cathode. The review focuses also on the role of technological advancements in nanomaterials as a performance improvement technique for new novel anode and cathode materials as well as on the discussion about lithium based and beyond lithium-based anode materials. In addition, the review offers rational cell and material design, perspectives, and future challenges to promote the application of these materials in practical lithium-ion batteries . With the coating PEDOT application, it is expected that the NMC-containing battery could either run at higher voltages, thus increasing their energy output, lifespans, or both. This work is reported in the journals [69,72].
The progress in energy storage requires new ways of thinking about LIBs and the fundamental limitations that different material chemistries impose. Research in electrochemistry presents a potential breakthrough advancement needed for the electrode and solid electrolyte materials to play a significant role in safer LIBs with longer life and higher efficiency. This would provide an explicit new understanding of the mechanism of Li-ion conduction and the through-space distance measurement between lithium spins in different environments [73,74]. The applications and further development of the different techniques during the last 30 years of diagnostic studies in LIBs and beyond cover critical technological developments and scientific challenges for a broad range of LIBs and beyond. The information that can be derived by applying different techniques to LIBs and beyond can be used to compare many families of suitable materials. Over the past decades, there have been many projections on the future depletion of the fossil fuel reserves on Earth as well as the rapid increase in green-house gas emissions . There is clearly an urgent need for the development of renewable energy technologies . Reliance on fossil-fuel energy led to countless resource wars worldwide and has resulted in the climate crisis we now face. Renewable energy sources such as wind or photovoltaic are intermittent, and their production peaks do not always follow the increasing demand. Therefore, storing green energy is essential to moving away from fossil fuels . On a different frontier, the growth, and manipulation of materials on the nanometer scale have progressed rapidly . Energy is the basic framework unifying the developing technologies for alternative green energy storage and conversion devices such as batteries, fuel cells, solar cells for transportation, stationary power and for distributed power generation applications . This framework is the only framework of its kind that allows a consistent treatment of the LIBs from electrodes and electrolytes to surfaces or solid-state electrode-electrolyte interface. LIBs are currently the staple of the video battery industry, and they have improved our life dramatically. LIBs are approaching their theoretical limits on achievable energy density and specific energy . If the market demand rises for even higher energy cells, then, the community must consider new technologies. The drawback of LIBs is due in part to the use of liquid organic electrolytes. While these organic electrolytes are necessary to the battery, they are highly flammable . However, what we need for the future is a new battery technology called solid-state battery (SSB), which promises greater safety, longer life, and faster charging . This is because SSBs contain non-flammable liquid electrolytes. In contrast, LIBs are charged with electricity generated when lithium-ion travels from cathode to anode. SSB technology is not new . Michael Faraday discovered the solid electrolytes silver sulfide and lead fluoride, which laid the foundation for solid-state research . In the late 1950s, efforts were initiated to develop a SSB, which failed due to design limitations . LIBs are at the center of the advanced rechargeable batteries and the scientific community has expanded an enormous effort to search for new electrode and electrolyte materials to enhance the amount of energy stored in electrochemical cells .
LIB development has a promising future as it lays in the intersection of improvement of cost-efficient energy storage, an ability to wean economies out of oil dependence, and critical components needed to fight and curb global warming . To look at the future of LIB development, we must look at the previous techniques and tools used in the battery science formation and how those tools have spilled over to other areas of physical science . We also must analyze the basic structural fundamentals of battery science and see if they still hold up to 30 years of development and research or if they should be modified or thrown out. LIB is very reactive and can withstand and achieve a high voltage rate. This makes it an interesting and an excellent choice for the battery revolution. Since, the growing needs of society are getting more and more demanding, LIBs are falling short due to the incapability of satisfying certain areas of societal needs. This shows that the question that one should ask is: Would LIBs still be the future knowing that obviously it does not satisfy major needs of interest? Researchers are looking forward to improving or increasing energy density for other lithium-based batteries other than LIB, such as lithium sulfur (Li-S) batteries and lithium-oxygen (Li-O2) . More recently, to provide more sustainable energy storage solutions, advancements have been made on sodium-Ion batteries (NIBs), potassium-ion batteries (KIBs) , and magnesium-ion batteries (MIBs) . These sustainable energies storage solutions with the use of NIBs, KIBs and MIBs are much more present and abundant than lithium. Moreover, they are promising prospects for large-scale grid energy storage. These facts are enough to conclude that LIBs are far from being the one lithium-based battery to resolve specific problems. Thus, the question of it being the future is inadequate! Researchers are looking for replacements of LIBs and researches show that many batteries can be candidates . For example, Na-based batteries are candidates for large-scale stationary energy storage applications. Other potential candidates such as the spinel Li1-xMn2O4 and the disordered rock-salt Li-Excess battery materials have been discovered to be ever-improving energy storage materials for the benefit of society [89,90,91]. LIBs are generally safe, but only so long as there are no defects and the batteries are not damaged. This presents some issues because a squandering of LIB can cause a lot of damage. We recall the incident with Samsung Galaxy Note 7, where the problem came from a slight flaw in the battery’s fabrication, which caused a lot of damage. The battery inside the phone was a lithium-based battery which means that it can present safety issues. Even though LIBs are failing to satisfy societal needs is the reason why researchers are looking beyond LIBs, it is important to mention that it has its advantages. LIBs are by far the most convenient ion-based battery in the industry, making them a product of preference among the other batteries . All electronic products now require a LIB for basic functioning. The practical benefits of the LIB are, without a doubt, compelling. The batteries are lighter in weight than most rechargeable battery alternatives, they hold their charge well, they have no memory effect, and they can handle hundreds of cycles of discharging/charging .
The cost of LIBs used to be high and now we are seeing a decrease in cost over the last few years. It's so happens that LIB has a lifespan for a large-capacity battery pack and can be as long as eight or more years . This shows that a LIB is the ideal battery when it comes to longevity because today, we need a battery that has a long lifespan for it to satisfy the modern society's needs in that area. LIBs compared to other batteries have the least impact on the environment. More and more research is being conducted and has been done to ever-improving battery understanding, especially lithium based-battery. The next step for the scientific community is to change perspective and start focusing on the other types of batteries that can satisfy societal needs rather than spending a lot of effort on LIBs again. It is about time to change direction and to use other techniques of application to other types of batteries to fill in the blank of what LIBs can no longer do. Four perspectives characterize the evolution from the conventional to the advanced LIBs (e.g., Li-rich transition metal oxide and Ni-rich transition metal oxide batteries), to the state of-the-art LIBs (e.g., Li-air, Li-sulfur batteries (LSBs), organic electrode batteries, solid-state batteries, and Li–CO2 batteries), and to the hybridized LIBs (e.g., metal halide perovskite batteries). LSB should be a promising candidate for the next generation of rechargeable batteries, but they are not without problems . The efficiency of charge transfer is low for lithium, and lithium batteries tend to grow dendrites, thin branching crystals when charging that do not disappear when discharged. Sulfur is the right battery of choice because it is inexpensive and has a high-charge capacity and a high energy density. For this reason, LSB has more energy. However, an LSB forms an inorganic coating in the battery that is brittle and cannot tolerate changes in volume . In LSB, the electrolyte dries up and the bulk lithium corrodes. The lithium dendrites that form can create short circuits and other safety hazards . Switching LIB from a flammable liquid electrolyte to a solid is not an easy task as lithium ions in solids are less mobile than in liquids. This lower mobility limits the battery performance in terms of charge and discharge rate. Scientists have been looking for materials that could enable all-SSBs. Recently, materials such as, LiTi2(PS4)3 or LTPS have been discovered . LTPS has the highest lithium diffusion coefficient ever measured in a solid. The lithium mobility comes directly from the unique crystal structure of LTPS. This mechanism opens new perspectives in the field of lithium ion conductors, and beyond LTPS, opens an avenue toward the search for new materials with similar diffusion mechanisms. This discovery is an important step in the understanding of materials needed for all-solid-state batteries of the future.
In addition of portable electronic devices, more perspectives on LIBs upon future developing techniques include in aerospace with applications in satellites and aviation .
Recently, Zubi et al. reported the LIBs technology that has the potential to be used in power supply systems, off-grid and grid-connected. Substantial improvements have been achieved in medical devices, such as in hearing aids, by exploiting the advances in lithium battery technology. This development has also guaranteed miniaturized, reliable, high density and hermetically sealed rechargeable power sources for highly integrated and size-limited low power implantable devices in applications such as drug-delivery, glucose sensing, and neuro-stimulation . The use of LIBs in medical devices has been explored, among others, by the US Food and Drug Administration . Many self-powered micro-electronics, such as miniature transistors, sensors and actuators also integrate tiny LIBs . Furthermore, as professionals continue to demand more powerful, efficient, and comfortable tools to work with, LIBs offer outstanding specific energy and power together with low self-discharge rates . Finally, Li-ion cells can also be found in wearable technology products, flashlights, radio-controlled toys, solar LED systems and wireless vacuum cleaners, among others .
The author would like to thank Drs. Thibault Charpentier and Vincent Battaglia, and Professors Robert Messinger and Bingwen Hu for helpful discussion. The author acknowledges the financial support from the City University of New York GRANT CCRG # 1517, PSC-CUNY RESEARCH AWARD # 62654-00 50, and CUNY RESEARCH SCHOLAR PROGRAM (2020-2021). The author appreciates the mentee’ students Fambougouri Diane, Daniel Bosah, Lamisa Rusmeha, Aissata Diop, Malik Pernarh, and Paulin Dongomale for reading the manuscript and helping in editing. The contents of this paper are solely the responsibility of the author and do not represent the official views of the NIH.
Eugene Mananga: Conceptualization, Writing – original draft, Writing – review & editing.
The authors have declared that no competing interests exist.
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