Strength Properties of Cellulosic Fibrous Mats Impregnated with Water Repellents Based on Reclaimed Polystyrene
Department of Forestry and Natural Environment, Laboratory of Forest Utilization, Aristotle University of Thessaloniki, 541 24 Thessaloniki, Greece
Department of Forest Biomaterials and Technology, Swedish University of Agricultural Sciences, Vallvägen 9D, 756 51 Uppsala, Sweden
Academic Editor: Ick Soo Kim
Received: August 23, 2022 | Accepted: October 20, 2022 | Published: October 28, 2022
Recent Progress in Materials 2022, Volume 4, Issue 4, doi:10.21926/rpm.2204022
Recommended citation: Foti D, Passialis C, Voulgaridis E, Adamopoulos S. Strength Properties of Cellulosic Fibrous Mats Impregnated with Water Repellents Based on Reclaimed Polystyrene. Recent Progress in Materials 2022; 4(4): 022; doi:10.21926/rpm.2204022.
© 2022 by the authors. This is an open access article distributed under the conditions of the Creative Commons by Attribution License, which permits unrestricted use, distribution, and reproduction in any medium or format, provided the original work is correctly cited.
Wood has many uses due to its unique structure and chemical composition. However, the hygroscopic nature of wood causes a fluctuation in its size and makes it susceptible to degradation by fungi and insect attacks, thus limiting its application in outdoor uses [1,2,3]. These limitations are overcome by performing impregnation with preservatives, chemical modification of wood, thermal treatments, and applying water repellents .
Water repellents are mixtures of various materials, such as resins, waxes, oils, and solvents. They may also contain small amounts of fungicides or insecticides. They have been extensively investigated and widely used to protect wooden structures from water uptake and fungal and insect attacks in outdoor or semi-outdoor settings [5,6,7]. Water repellents are applied using conventional impregnation techniques and deposited in wood capillaries. Thus, they fill in the lumens and form thin films on pore surfaces . The non-polar agents in water repellents cannot establish chemical linking with the cell wall polymers, and thus, they only work as a physical barrier. Hence, they can reduce the water adsorption rate but not the final moisture content . Paraffin wax is the most common synthetic water repellent used in the wood industry . Eco-friendly water repellents with promising chemical and physical composition based on wood extractives and natural resins (oleoresin, gum rosin, tall oil fractions, etc.) have been investigated. These alternative green materials were investigated in solid wood, fiber-based matrices, and wood composites, and their effectiveness was found to be comparable to that of traditional synthetic water repellents [11,12,13,14,15,16,17].
The increase in environmental awareness and associated policies have encouraged the use of renewable substances, including recycled materials, for wood protection. Reclaimed polystyrene can repel wood specimens and particleboards more effectively than commercial water repellents [18,19]. Studies on the water-repellent properties of formulations based on reclaimed polystyrene, alkyd resin, gum rosin, and paraffin wax have shown promising results . In this study, we investigated the above-mentioned formulations and determined the strength properties of cellulosic fibrous mats using the deposited water-repellent films.
2. Materials and Methods
2.1 Preparation of Formulations
The composition of the experimental water-repellent solutions was based on reclaimed polystyrene (styrofoam, expanded polystyrene-EPS in the form of insulating thermal and acoustical foam boards), alkyd resin (alkydal FSOW/63% in butyl glycol; Bayer, Germany), paraffin wax (with a melting point of 55 °C), and gum rosin (quality WW) produced by distilling Aleppo pine oleoresin . The substances were diluted in different proportions of commercial nitro and toluene solvents (Pansil Industry of Chemical Products, Attica, Greece). Upon macroscopic inspection, the water-repellent solutions were completely diluted in the solvent in room temperature, for at least 48 h, and they remained clear after gentle agitation. In total, 24 water-repellent formulations were prepared, as shown in Table 1.
2.2 Testing of Paper Samples
Filter paper samples (12 × 12 cm2 and 60 g/m2 of grammage) were impregnated by immersion in the water-repellent formulations for 3 min. Next, the samples were air-dried in a horizontal position for solvent evaporation. Ten samples were impregnated with each formulation. After air-drying and conditioning the samples at 23 ±1 °C and 50 ±2% RH according to the SCAN-P2:75 standard, the impregnated filter paper samples were used for determining grammage and strength properties, including bursting strength, resistance to bending, the ring crush resistance (RCT), and the compression strength (SCT), according to corresponding SCAN and ISO standards (Table 2).
The characteristics of fractured surfaces after the bursting strength tests were observed under an SMZ-800 stereomicroscope (Nikon, Tokyo, Japan) at 5x magnification using stripes. One-way analysis of variance (ANOVA) of the strength values was performed using the software program IBM® SPSS® Statistics, version 24.0. The statistical differences between the values were evaluated by performing Tukey’s honestly significant difference (HSD) test at an error probability of α = 0.05. The statistical analysis was conducted only for those formulations that exhibited better strength properties, i.e., formulations based on 20% polystyrene (see Table 3).
3. Results and Discussion
The results related to the grammage and strength properties of the impregnated filter papers were shown in Table 3. The relationships between concentration and retention and between retention and grammage were investigated in another study . For all formulations, retention increased with the increase in concentration, and the increase in retention led to an increase in grammage. Grammage or basis weight (the weight per unit area expressed as g/m2), is an estimator of the influence of the bulk structure of paper on its strength . The effect of grammage on the strength properties is illustrated in Figure 1. For all strength properties determined, an increase in strength was associated with an increase in the grammage.
Figure 1 The relationship between strength and grammage. The symbols are explained in Table 1.
After performing the bursting strength test, low magnification (5x) fractured surfaces revealed details of fiber failures (Figure 2).
Figure 2 Fractured surfaces of filter papers after the bursting strength tests were performed. The symbols are explained in Table 1; scale bars = 10 mm.
Such interfiber fractures are considered to be a supplementary assessment of the bonding quality among treated cellulosic fibers . At low solid concentrations (5–10%), the fibers separated from each other at the edges of the fracture. At higher concentrations (15–20%), the formulations decreased the porosity of the cellulosic fibrous mats, and the fibers broke (see Figure 2). This failure mode of the fibers (breakage) might be associated with better mechanical properties of the filter paper samples impregnated with solutions containing high concentrations of solid (see Table 3). Since the filter paper matrix was immersed in the water-repellent solutions, the mechanical strength of the impregnated filter papers depended on the matrix, the water-repellent film, and the interfacial adhesion between them. Higher concentrations of the formulations provided greater strength by encompassing the fiber network and further fortifying it. In contrast to the strong films produced by the formulations based on reclaimed polystyrene, films with poor mechanical strength and low fiber-fiber interactions are produced when a high level of paraffin wax is used [16,17,28,29].
The strength properties only of those formulations in which the polystyrene content was 20% are shown in Figure 3.
Figure 3 Strength values of filter paper samples impregnated with formulations based on reclaimed polystyrene with 20% solid content. Strength values with the same letter are significantly different, as determined by ANOVA and Tukey’s HSD test. The symbols are explained in Table 1.
Based on Table 3 and Figure 3, the most effective formulations related to the bursting and bending strengths were those that combined reclaimed polystyrene with alkyd resin (formulation C) and gum rosin with paraffin wax (formulation F). When paraffin wax was added either to reclaimed polystyrene only (formulation B) or reclaimed polystyrene and alkyd resin (formulation D), the strength decreased. Regarding compression strength (SCT), formulation F had the second-highest bursting and bending strengths, while formulation E (reclaimed polystyrene and gum rosin) had the highest bursting and bending strengths. This differentiation might be due to the differences in the load applied in these tests and the failure characteristics of the developed matrices. For RCT, formulation F was the best. Hence, formulation F might be the most preferable since it combines strength and hydrophobicity . Overall, the results indicated that water-repellent formulations based on reclaimed polystyrene might be used for effectively enhancing the performance of cellulosic fibers, which is a key step for their efficient use in sustainable products. The results of the statistical analysis showed that significant differences occurred between formulations C and E and formulations E and F for busting strength; between formulations A and E and formulations C and E for RCT; between formulations A and E and formulations C and E for SCT. However, no significant differences were found in the bending strength between samples (see Figure 3).
The conclusions of this study can be summarized as follows:
- Water-repellent formulations with high concentrations of solid ingredients increased the retention, grammage, and strength properties of impregnated fibrous mats.
- The formulations that most effectively increased overall strength performance were those containing 20% reclaimed polystyrene.
- Regarding bursting and bending strength, formulations containing alkyd resin were better than those containing gum rosin.
- The formulations with gum rosin performed better than those containing alkyd resin in the RCT and SCT.
- Adding paraffin in formulations with high concentrations of reclaimed polystyrene (20%) and gum rosin did not affect the strength properties.
Conceptualization, D.F., C.P. and S.A.; methodology, D.F., C.P., E.V. and S.A.; investigation, D.F. and C.P.; data curation, D.F.; writing-original draft preparation, D.F.; writing-review and editing, S.A., D.F., C.P. and E.V.; supervision, C.P. and S.A. All authors have read and agreed to the published version of the manuscript.
The authors have declared that no competing interests exist.
- Hartley I, Hamza MF. Wood: Moisture content, hygroscopicity, and sorption. In: Reference module in materials science and materials engineering. 1st ed. Oxford: Elsevier; 2016. pp. 1-7. [CrossRef]
- Sargent R. Evaluating dimensional stability in solid wood: A review of current practice. J Wood Sci. 2019; 65: 36. [CrossRef]
- Brischke C, Alfredsen G. Wood-water relationships and their role for wood susceptibility to fungal decay. Appl Microbiol Biotechnol. 2020; 104: 3781-3795. [CrossRef]
- Cheremisinoff NP, Rosenfeld PE. Chapter 2 - Wood-preserving technology. In: Handbook of pollution prevention and cleaner production: Best practices in the wood and paper industries. 1st ed. Oxford: William Andrew Publishing; 2010. pp. 27-41. [CrossRef]
- Banks WB, Voulgaridis EV. The performance of water repellents in the control of moisture absorption by wood exposed to the weather. Proceedings of the 1980 Annual Convention of the British Wood Preserving Association; 1980 June 24-27; London, UK.
- Rowell RM, Bank WB. Water repellency and dimensional stability of wood. Madison, WI, US Department of Agriculture, Forest Service, Forest Products Laboratory; 1985. Gen Tech Rep FPL-50.
- Williams RS, Feist WC. Water repellents and water-repellent preservatives for wood. Madison, WI: US Department of Agriculture, Forest Service, Forest Products Laboratory; 1999. Gen Tech Rep FPL-GTR-109. [CrossRef]
- Scholz G, Adamopoulos S, Militz H. Migration of blue stain hyphae within wax treated wood. IAWA J. 2011; 32: 88-96. [CrossRef]
- Chen J, Wang Y, Cao J, Wang W. Improved water repellency and dimensional stability of wood via impregnation with an epoxidized linseed oil and Carnauba wax complex emulsion. Forests. 2020; 11: 271. [CrossRef]
- Evans PD, Wingate-Hill R, Cunningham RB. Wax and oil emulsion additives: How effective are they at improving the performance of preservative-treated wood? Forest Prod J. 2009; 59: 66-70.
- Voulgaridis E. Protection of oak wood (Quercus conferta Kit.) from liquid water uptake with water reppelents. Wood Fiber Sci. 1988; 20: 68-73.
- Grigoriou A, Passialis C. Gum rosin as water-repellent additive for particleboards. Holzforsch Holzverw. 1990; 42: 93-94.
- Voulgaridis E. Oleoresin and gum rosin from Pinus halepensis Mill. as basic continuents in water repellent formulations applied to wood. Holz Roh Werkst. 1993; 51: 324-328. [CrossRef]
- van Eckeveld A, Homan WJ, Militz H. Increasing the water repelllency of Scots pine sapwood by impregnation with undiluted linseed oil, wood oil, coccos oil, tall oil. Holzforsch Holzverw. 2001; 6: 113-115.
- Hyvönen A, Piltonen P, Niinimäki J. Tall oil/water – emulsions as water repellents for Scots pine sapwood. Holz Roh Werkst. 2006; 64: 68-73. [CrossRef]
- Hosseinpourpia R, Adamopoulos S, Parsland P. Utilization of different tall oils for improving the water resistance of cellulosic fibers. J Appl Polym Sci. 2019; 136: 47303-47310. [CrossRef]
- Hosseinpourpia R, Adamopoulos S, Walther T, Naydenov V. Hydrophobic formulations based on tall oil distillation products for high-density fiberboards. Materials. 2020; 13: 4025. [CrossRef]
- Voulgaridis E, Passialis C. Preliminary studies on water repellent properties of reclaimed polystyrene applied to small wood specimens. Holzforsch Holzverw. 1982; 34: 66-69.
- Passialis C. Improving the properties of particleboards by impregnation with a toluene-based polystyrene solution. Holz Roh Werkst. 1986; 44: 193-195. [CrossRef]
- Foti D, Passialis C, Voulgaridis E, Adamopoulos S. Water repellency of cellulosic fibrous mats impregnated with organic solutions based on recycled polystyrene. J Renew Mater. 2021; 9: 85-96. [CrossRef]
- SCAN-P 6:75. Grammage. Stockholm: Scandinavian Pulp, Paper and Board Testing Committee; 1995.
- SCAN-P 25:81. Bursting strength. Stockholm: Scandinavian Pulp, Paper and Board Testing Committee; 1995.
- ISO 2493. Determination of resistance to bending. Geneva: International Organization for Standardization; 1992.
- SCAN-P 34:71. Ring crush resistance of paper and paperboard. Stockholm: Scandinavian Pulp, Paper and Board Testing Committee; 1995.
- SCAN-P 46:83. Compression strength short span test. Stockholm: Scandinavian Pulp, Paper and Board Testing Committee; 1995.
- Adamopoulos S, Passialis C, Voulgaridis E, Oliver JV. Grammage and structural density as quality indexes of packaging grade papers manufactured from recycled pulps. Drewno. 2014; 57: 145-151.
- Adamopoulos S, Hosseinpourpia R, Mai C. Tensile strength of handsheets prepared with macerated fibres from solid wood modified with cross-linking agents. Holzforschung. 2015; 69: 959-966. [CrossRef]
- Gustafsson E, Larsson PA, Wågberg L. Treatment of cellulose fibres with polyelectrolytes and wax colloids to create tailored highly hydrophobic fibrous networks. Colloids Surf A. 2012; 414: 415-421. [CrossRef]
- Wang DX, Chen SS, Jin SH, Shu QH, Jiang ZM, Shang FQ, et al. Investigation into the coating and desensitization effect on HNIW of paraffin wax/stearic acid composite systems. J Energ Mater. 2016; 34: 26-37. [CrossRef]