Acetonitrile Combustion over Copper-Based Nanocatalysts: A Structure-Performance Relationship Study
Abstract
1530 9656
Acetonitrile Combustion over Copper-Based Nanocatalysts: A Structure-Performance Relationship StudyAbstract
In this paper, the relationship between activity and structure of Cu2+ in different chemical environments of Cu-BETA, La2CuO4, and CuO nanocatalysts was systematically investigated for acetonitrile combustion. The study revealed that exchanged and octahedral species of Cu2+ coexist in Cu-BETA, while octahedral species are dominant in CuO and La2CuO4. All nanocatalysts achieved high conversion rates of acetonitrile, which rapidly increased with temperature. CuO and La2CuO4 led to the formation of undesired products [...] 1530 9656 |
Versatility of Supported Gold Nanoparticles on Hydrotalcites used for Oxidation and Reduction Reactionsby
Abstract
Regardless of their size, supported gold nanoparticles are largely used for liquid-phase oxidation reactions. Small gold nanoparticles exhibit good performance during the reduction of organic compounds. The direct reduction of carboxylic acid to aldehyde is a famous and familiar reaction in the field of organic chemistry and is considered as one of the fundamental chemical transformations. Herein, we present Au/hydrotalcite, Au/MgO, and Au/Al2O3 systems as heterogeneous versatile catalysts to realize the oxidation [...] 1584 10847 |
Effect of Acid Treatment on the Properties of Zeolite Catalyst for Straight-Run Gasoline UpgradingAbstract
The objective of this research was to analyze the effect of different concentrations of nitric and hydrochloric acids on the structural, acidic, and catalytic properties of a post-synthetic treated ZSM-5 type zeolite at various temperatures. The properties of zeolite catalysts were determined using different methods, such as the Brunauer-Emmett-Teller (BET) method for specific surface area, temperature-programmed desorption (TPD) of ammonia method for acidic properties, and a flow-through unit with fixed bed cataly [...] 3215 17275 |
Stability of a Fe-Rich Cathode Catalyst in an Anion Exchange Membrane Fuel Cellby
Abstract
Fe-rich alloys have been widely studied as catalyst materials for the cathodic oxygen reduction reaction (ORR) in hydrogen fuel cells, and many have shown high activities. The stability of Fe-rich catalysts has also been researched, and some studies have shown promising results using an accelerated stress test (AST), which uses a potential cycling method. However, for commercial fuel cell applications, such as standby power systems, the catalyst has to tolerate a high potential for a long period, which can not be r [...] 1371 10694 |
Photocatalytic Degradation of Azo Dyes Using Microreactors: Mechanistic Study of its Effects on H2O2 AdditionAbstract
The photocatalytic reaction involved in TiO2 photocatalysis was investigated using a microreactor coated with TiO2 film on the glass plate attached on one side of the microreactor. It was confirmed that the effect of H2O2 on the photocatalytic degradation efficiency of azo dyes (acid orange 7, acid red 151, and acid yellow 23) was dependent on the polymorphs (anatase and rutile) of TiO2 coated on the glass plate of the UV-irradiated microreactor. Scavengers of holes (KI) and electrons (p-benzoquinone) were added to [...] 2016 12544 |
Development of an Efficient Bi-Functional Catalyst made of a Novel Hybrid Material for Rechargeable Zn-Air BatteryAbstract
One-pot synthesis of mesoporous hybrid material consisting of Mn-Co/CoO nanoparticles encapsulated in an N-doped graphene shell decorated with Mo2C nanoparticles (Mo2C-NC@Mn-Co/CoO) was reported. The Mn and Mo components synergistically refined the graphitized carbons due to the interactions with N and C atoms while promoting the stability of the Co/CoO nanoparticles. These components exhibited a beneficial effect on the dispersion of the active metal/metal oxide nanoparticles and the formation of a mesoporous stru [...] 4285 16409 |
Restoring the Resilience of Water-Energy-Food Nexus Based on Desalination through Biomass Management: Case Study West Mani, Greeceby
Abstract
Mediterranean regions like West Mani, Greece, face escalating water scarcity exacerbated by climate variability and seasonal tourism peaks, straining the water-energy-food (WEF) nexus. Olive cultivation, central to the region’s economy and culture, generates substantial underutilized biomass residues that increase wildfire risk if left unmanaged. At the same time, water supply increasingly relies on energy-intensive desalination and pumping. This study addresses the gap in integrated, place-based WEF nexus applicat [...] 236 627 |
Hydroclimatic Variability and Precipitation Extremes in Sindh under a Changing ClimateAbstract
Sindh Province, Pakistan, is highly vulnerable to hydroclimatic extremes, necessitating a detailed understanding of its precipitation patterns for effective water management. This study assesses spatiotemporal precipitation dynamics across Sindh from 2001 to 2024 by integrating satellite-based CHIRPS data, in situ observations from the Climate Knowledge Portal (CKP), and CMIP6 climate model projections. Validation results show strong agreement between CHIRPS and ground data (R ≈ 0.87, d ≈ 0.93), confirming the sate [...] 282 744 |
Characterization of Drought Severity Using GRACE and TerraClimate Dataset in the Rift Valley Basin, EthiopiaAbstract
Characterizing drought severity using GRACE and TerraClimate datasets is globally important because it enables consistent, large-scale monitoring of both surface and subsurface water availability across data-scarce regions. This integrated perspective supports improved drought assessment, climate change impact analysis, and informed water-resource management worldwide. The Ethiopian Rift Valley has experienced recurrent hydrological drought hazards, posing serious threats to water availability, agricultural product [...] 318 949 |
Contribution of Solar Energy to Buildings’ Energy Demands: A Reviewby
Abstract
Buildings account for a significant portion of global energy consumption, estimated at 30-40%, and also contribute to greenhouse gas emissions. Energy consumption in a building is mainly thermal (natural gas) and electrical. This energy is usually used for heating water, cooking, illumination, ventilation and air conditioning, powering appliances, floor heating, and other activities. These activities were examined, and their substitution by solar-based energy sources was reviewed. To achieve this objective, an exte [...] 679 1862 |
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