TY  - JOUR
AU  - Huang, Louguangshu
AU  - Liu, Hui
AU  - Xue, Xiaoxia
AU  - Zhao, Wuduo
AU  - Li, Tiesheng
PY  - 2022
DA  - 2022/02/03
TI  - Controllable Cyclopalladated Polythiophene Imine Monolayer by Self-Assembly, Hybrid Doping and Electrochemical Polymerization: A Simple Way to Enhance Activity and Stability
JO  - Catalysis Research
SP  - 003
VL  - 02
IS  - 01
AB  - In this article, an approach to generate self-assembly cyclopalladated polythiophene imine monolayers (denoted as ITO@Pd-CPTIMs) is described. The monolayers were fabricated by combining self-assembly (SA), hybrid doping (HD), and electrochemical polymerization (ECP) called SA-HD-ECP. The catalytic activity and stability of the polymerized monolayers in the Suzuki coupling reaction were improved by modulating the structure and morphology in hybrid doping using different thiophene derivatives, concentrations, and scanning numbers during electrochemical polymerization. Morphological changes in the catalytic surface associated with catalytic activity were investigated.  ITO@Pd-PTF could improve catalytic activity with a higher TON value (45000 mol/molcat) and attain recycling ability at least 10 times.
SN  - 2771-490X
UR  - https://doi.org/10.21926/cr.2201003
DO  - 10.21926/cr.2201003
ID  - Huang2022
ER  -